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Wide-gamut lasing from a single organic chromophore

The development of wideband lasing media has deep implications for imaging, sensing, and display technologies. We show that a single chromophore can be engineered to feature wide-gamut fluorescence and lasing throughout the entire visible spectrum and beyond. This exceptional color tuning demonstrat...

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Autores principales: Lane, S., Vagin, S., Wang, H., Heinz, W. R., Morrish, W., Zhao, Y., Rieger, B., Meldrum, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6279737/
https://www.ncbi.nlm.nih.gov/pubmed/30534370
http://dx.doi.org/10.1038/s41377-018-0102-1
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author Lane, S.
Vagin, S.
Wang, H.
Heinz, W. R.
Morrish, W.
Zhao, Y.
Rieger, B.
Meldrum, A.
author_facet Lane, S.
Vagin, S.
Wang, H.
Heinz, W. R.
Morrish, W.
Zhao, Y.
Rieger, B.
Meldrum, A.
author_sort Lane, S.
collection PubMed
description The development of wideband lasing media has deep implications for imaging, sensing, and display technologies. We show that a single chromophore can be engineered to feature wide-gamut fluorescence and lasing throughout the entire visible spectrum and beyond. This exceptional color tuning demonstrates a chemically controlled paradigm for light emission applications with precise color management. Achieving such extensive color control requires a molecular blueprint that yields a high quantum efficiency and a high solubility in a wide variety of liquids and solids while featuring a heterocyclic structure with good steric access to the lone pair electrons. With these requirements in mind, we designed a lasing chromophore that encloses a lasing color space twice as large as the sRGB benchmark. This record degree of color tuning can in principle be adapted to the solid state by incorporating the chromophore into polymer films. By appropriately engineering the base molecular structure, the widest range of lasing wavelengths observed for a conventional gain medium can be achieved, in turn establishing a possible route toward high-efficiency light emitters and lasers with near-perfect chromaticity.
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spelling pubmed-62797372018-12-10 Wide-gamut lasing from a single organic chromophore Lane, S. Vagin, S. Wang, H. Heinz, W. R. Morrish, W. Zhao, Y. Rieger, B. Meldrum, A. Light Sci Appl Article The development of wideband lasing media has deep implications for imaging, sensing, and display technologies. We show that a single chromophore can be engineered to feature wide-gamut fluorescence and lasing throughout the entire visible spectrum and beyond. This exceptional color tuning demonstrates a chemically controlled paradigm for light emission applications with precise color management. Achieving such extensive color control requires a molecular blueprint that yields a high quantum efficiency and a high solubility in a wide variety of liquids and solids while featuring a heterocyclic structure with good steric access to the lone pair electrons. With these requirements in mind, we designed a lasing chromophore that encloses a lasing color space twice as large as the sRGB benchmark. This record degree of color tuning can in principle be adapted to the solid state by incorporating the chromophore into polymer films. By appropriately engineering the base molecular structure, the widest range of lasing wavelengths observed for a conventional gain medium can be achieved, in turn establishing a possible route toward high-efficiency light emitters and lasers with near-perfect chromaticity. Nature Publishing Group UK 2018-12-05 /pmc/articles/PMC6279737/ /pubmed/30534370 http://dx.doi.org/10.1038/s41377-018-0102-1 Text en © The Author(s) 2018 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Lane, S.
Vagin, S.
Wang, H.
Heinz, W. R.
Morrish, W.
Zhao, Y.
Rieger, B.
Meldrum, A.
Wide-gamut lasing from a single organic chromophore
title Wide-gamut lasing from a single organic chromophore
title_full Wide-gamut lasing from a single organic chromophore
title_fullStr Wide-gamut lasing from a single organic chromophore
title_full_unstemmed Wide-gamut lasing from a single organic chromophore
title_short Wide-gamut lasing from a single organic chromophore
title_sort wide-gamut lasing from a single organic chromophore
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6279737/
https://www.ncbi.nlm.nih.gov/pubmed/30534370
http://dx.doi.org/10.1038/s41377-018-0102-1
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