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Crystal structure of the lead-containing organic–inorganic hybrid: (C(18)H(26)N(2))(3)[Pb(4)I(14)(DMSO)(2)]·2DMSO
The title compound, tris(1,1′-dibutyl-4,4′-bipyridine-1,1′-diium) bis(dimethyl sulfoxide)di-μ(3)-iodido-tetra-μ(2)-iodido-octaiodidotetralead(II) dimethyl sulfoxide disolvate, (C(18)H(26)N(2))(3)[Pb(4)I(14)(C(2)H(6)OS)(2)]·2C(2)H(6)OS, belongs to a class of organic–inorganic hybrid materials...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6281093/ https://www.ncbi.nlm.nih.gov/pubmed/30574392 http://dx.doi.org/10.1107/S2056989018016584 |
| Sumario: | The title compound, tris(1,1′-dibutyl-4,4′-bipyridine-1,1′-diium) bis(dimethyl sulfoxide)di-μ(3)-iodido-tetra-μ(2)-iodido-octaiodidotetralead(II) dimethyl sulfoxide disolvate, (C(18)H(26)N(2))(3)[Pb(4)I(14)(C(2)H(6)OS)(2)]·2C(2)H(6)OS, belongs to a class of organic–inorganic hybrid materials with novel functionalities. In this compound, C—H⋯O and C—H⋯I hydrogen-bonding interactions, π–π interactions, other short contacts and Pb octahedral chains are present, extending the crystal structure into a three-dimensional supramolecular network. |
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