Crystal structure of the lead-containing organic–inorganic hybrid: (C(18)H(26)N(2))(3)[Pb(4)I(14)(DMSO)(2)]·2DMSO

The title compound, tris­(1,1′-dibutyl-4,4′-bi­pyridine-1,1′-diium) bis­(dimethyl sulfoxide)di-μ(3)-iodido-tetra-μ(2)-iodido-octa­iodido­tetra­lead(II) dimethyl sulfoxide di­solvate, (C(18)H(26)N(2))(3)[Pb(4)I(14)(C(2)H(6)OS)(2)]·2C(2)H(6)OS, belongs to a class of organic–inorganic hybrid materials...

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Autores principales: Li, Li, Zhao, Dan, Liu, Zhi, Zhang, Dingchao, Hu, Zhenhao, Li, Kunlun, Yang, Jing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6281093/
https://www.ncbi.nlm.nih.gov/pubmed/30574392
http://dx.doi.org/10.1107/S2056989018016584
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author Li, Li
Zhao, Dan
Liu, Zhi
Zhang, Dingchao
Hu, Zhenhao
Li, Kunlun
Yang, Jing
author_facet Li, Li
Zhao, Dan
Liu, Zhi
Zhang, Dingchao
Hu, Zhenhao
Li, Kunlun
Yang, Jing
author_sort Li, Li
collection PubMed
description The title compound, tris­(1,1′-dibutyl-4,4′-bi­pyridine-1,1′-diium) bis­(dimethyl sulfoxide)di-μ(3)-iodido-tetra-μ(2)-iodido-octa­iodido­tetra­lead(II) dimethyl sulfoxide di­solvate, (C(18)H(26)N(2))(3)[Pb(4)I(14)(C(2)H(6)OS)(2)]·2C(2)H(6)OS, belongs to a class of organic–inorganic hybrid materials with novel functionalities. In this compound, C—H⋯O and C—H⋯I hydrogen-bonding inter­actions, π–π inter­actions, other short contacts and Pb octa­hedral chains are present, extending the crystal structure into a three-dimensional supra­molecular network.
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spelling pubmed-62810932018-12-20 Crystal structure of the lead-containing organic–inorganic hybrid: (C(18)H(26)N(2))(3)[Pb(4)I(14)(DMSO)(2)]·2DMSO Li, Li Zhao, Dan Liu, Zhi Zhang, Dingchao Hu, Zhenhao Li, Kunlun Yang, Jing Acta Crystallogr E Crystallogr Commun Research Communications The title compound, tris­(1,1′-dibutyl-4,4′-bi­pyridine-1,1′-diium) bis­(dimethyl sulfoxide)di-μ(3)-iodido-tetra-μ(2)-iodido-octa­iodido­tetra­lead(II) dimethyl sulfoxide di­solvate, (C(18)H(26)N(2))(3)[Pb(4)I(14)(C(2)H(6)OS)(2)]·2C(2)H(6)OS, belongs to a class of organic–inorganic hybrid materials with novel functionalities. In this compound, C—H⋯O and C—H⋯I hydrogen-bonding inter­actions, π–π inter­actions, other short contacts and Pb octa­hedral chains are present, extending the crystal structure into a three-dimensional supra­molecular network. International Union of Crystallography 2018-11-27 /pmc/articles/PMC6281093/ /pubmed/30574392 http://dx.doi.org/10.1107/S2056989018016584 Text en © Li et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Li, Li
Zhao, Dan
Liu, Zhi
Zhang, Dingchao
Hu, Zhenhao
Li, Kunlun
Yang, Jing
Crystal structure of the lead-containing organic–inorganic hybrid: (C(18)H(26)N(2))(3)[Pb(4)I(14)(DMSO)(2)]·2DMSO
title Crystal structure of the lead-containing organic–inorganic hybrid: (C(18)H(26)N(2))(3)[Pb(4)I(14)(DMSO)(2)]·2DMSO
title_full Crystal structure of the lead-containing organic–inorganic hybrid: (C(18)H(26)N(2))(3)[Pb(4)I(14)(DMSO)(2)]·2DMSO
title_fullStr Crystal structure of the lead-containing organic–inorganic hybrid: (C(18)H(26)N(2))(3)[Pb(4)I(14)(DMSO)(2)]·2DMSO
title_full_unstemmed Crystal structure of the lead-containing organic–inorganic hybrid: (C(18)H(26)N(2))(3)[Pb(4)I(14)(DMSO)(2)]·2DMSO
title_short Crystal structure of the lead-containing organic–inorganic hybrid: (C(18)H(26)N(2))(3)[Pb(4)I(14)(DMSO)(2)]·2DMSO
title_sort crystal structure of the lead-containing organic–inorganic hybrid: (c(18)h(26)n(2))(3)[pb(4)i(14)(dmso)(2)]·2dmso
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6281093/
https://www.ncbi.nlm.nih.gov/pubmed/30574392
http://dx.doi.org/10.1107/S2056989018016584
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