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Crystal structure and Hirshfeld surface analysis of (succinato-κO)[N,N,N′,N′-tetra­kis­(2-hy­droxy­eth­yl)ethyl­enedi­amine-κ(5) O,N,N′,O′,O′′]nickel(II) tetra­hydrate

In the title compound, [Ni(C(10)H(24)N(2)O(4))(C(4)H(4)O(4))]·4H(2)O, the Ni(II) cation is octa­hedrally coordinated by one O atom of the succinate anion and three O atoms and two N atoms from an N,N,N′,N′-tetra­kis­(2-hy­droxy­eth­yl)ethyl­enedi­amine mol­ecule. In the crystal, mol­ecules are linke...

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Detalles Bibliográficos
Autores principales: Kansiz, Sevgi, Dege, Necmi, Topcu, Yildiray, Atalay, Yusuf, Gaidai, Snizhana V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6281127/
https://www.ncbi.nlm.nih.gov/pubmed/30574359
http://dx.doi.org/10.1107/S2056989018015359
Descripción
Sumario:In the title compound, [Ni(C(10)H(24)N(2)O(4))(C(4)H(4)O(4))]·4H(2)O, the Ni(II) cation is octa­hedrally coordinated by one O atom of the succinate anion and three O atoms and two N atoms from an N,N,N′,N′-tetra­kis­(2-hy­droxy­eth­yl)ethyl­enedi­amine mol­ecule. In the crystal, mol­ecules are linked by O—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular architecture. Hirshfeld surface analyses and two-dimensional fingerprint plots were used to analyse the inter­molecular inter­actions present in the crystal, indicating that the most important contributions for the crystal packing are from H⋯H (63.3%) and H⋯O/O⋯H (34.5%) inter­actions.