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Crystal structure and Hirshfeld surface analysis of (succinato-κO)[N,N,N′,N′-tetrakis(2-hydroxyethyl)ethylenediamine-κ(5) O,N,N′,O′,O′′]nickel(II) tetrahydrate
In the title compound, [Ni(C(10)H(24)N(2)O(4))(C(4)H(4)O(4))]·4H(2)O, the Ni(II) cation is octahedrally coordinated by one O atom of the succinate anion and three O atoms and two N atoms from an N,N,N′,N′-tetrakis(2-hydroxyethyl)ethylenediamine molecule. In the crystal, molecules are linke...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6281127/ https://www.ncbi.nlm.nih.gov/pubmed/30574359 http://dx.doi.org/10.1107/S2056989018015359 |
Sumario: | In the title compound, [Ni(C(10)H(24)N(2)O(4))(C(4)H(4)O(4))]·4H(2)O, the Ni(II) cation is octahedrally coordinated by one O atom of the succinate anion and three O atoms and two N atoms from an N,N,N′,N′-tetrakis(2-hydroxyethyl)ethylenediamine molecule. In the crystal, molecules are linked by O—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional supramolecular architecture. Hirshfeld surface analyses and two-dimensional fingerprint plots were used to analyse the intermolecular interactions present in the crystal, indicating that the most important contributions for the crystal packing are from H⋯H (63.3%) and H⋯O/O⋯H (34.5%) interactions. |
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