Crystal structure and Hirshfeld surface analysis of (succinato-κO)[N,N,N′,N′-tetra­kis­(2-hy­droxy­eth­yl)ethyl­enedi­amine-κ(5) O,N,N′,O′,O′′]nickel(II) tetra­hydrate

In the title compound, [Ni(C(10)H(24)N(2)O(4))(C(4)H(4)O(4))]·4H(2)O, the Ni(II) cation is octa­hedrally coordinated by one O atom of the succinate anion and three O atoms and two N atoms from an N,N,N′,N′-tetra­kis­(2-hy­droxy­eth­yl)ethyl­enedi­amine mol­ecule. In the crystal, mol­ecules are linke...

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Autores principales: Kansiz, Sevgi, Dege, Necmi, Topcu, Yildiray, Atalay, Yusuf, Gaidai, Snizhana V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6281127/
https://www.ncbi.nlm.nih.gov/pubmed/30574359
http://dx.doi.org/10.1107/S2056989018015359
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author Kansiz, Sevgi
Dege, Necmi
Topcu, Yildiray
Atalay, Yusuf
Gaidai, Snizhana V.
author_facet Kansiz, Sevgi
Dege, Necmi
Topcu, Yildiray
Atalay, Yusuf
Gaidai, Snizhana V.
author_sort Kansiz, Sevgi
collection PubMed
description In the title compound, [Ni(C(10)H(24)N(2)O(4))(C(4)H(4)O(4))]·4H(2)O, the Ni(II) cation is octa­hedrally coordinated by one O atom of the succinate anion and three O atoms and two N atoms from an N,N,N′,N′-tetra­kis­(2-hy­droxy­eth­yl)ethyl­enedi­amine mol­ecule. In the crystal, mol­ecules are linked by O—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular architecture. Hirshfeld surface analyses and two-dimensional fingerprint plots were used to analyse the inter­molecular inter­actions present in the crystal, indicating that the most important contributions for the crystal packing are from H⋯H (63.3%) and H⋯O/O⋯H (34.5%) inter­actions.
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spelling pubmed-62811272018-12-20 Crystal structure and Hirshfeld surface analysis of (succinato-κO)[N,N,N′,N′-tetra­kis­(2-hy­droxy­eth­yl)ethyl­enedi­amine-κ(5) O,N,N′,O′,O′′]nickel(II) tetra­hydrate Kansiz, Sevgi Dege, Necmi Topcu, Yildiray Atalay, Yusuf Gaidai, Snizhana V. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Ni(C(10)H(24)N(2)O(4))(C(4)H(4)O(4))]·4H(2)O, the Ni(II) cation is octa­hedrally coordinated by one O atom of the succinate anion and three O atoms and two N atoms from an N,N,N′,N′-tetra­kis­(2-hy­droxy­eth­yl)ethyl­enedi­amine mol­ecule. In the crystal, mol­ecules are linked by O—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular architecture. Hirshfeld surface analyses and two-dimensional fingerprint plots were used to analyse the inter­molecular inter­actions present in the crystal, indicating that the most important contributions for the crystal packing are from H⋯H (63.3%) and H⋯O/O⋯H (34.5%) inter­actions. International Union of Crystallography 2018-11-06 /pmc/articles/PMC6281127/ /pubmed/30574359 http://dx.doi.org/10.1107/S2056989018015359 Text en © Kansiz et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Kansiz, Sevgi
Dege, Necmi
Topcu, Yildiray
Atalay, Yusuf
Gaidai, Snizhana V.
Crystal structure and Hirshfeld surface analysis of (succinato-κO)[N,N,N′,N′-tetra­kis­(2-hy­droxy­eth­yl)ethyl­enedi­amine-κ(5) O,N,N′,O′,O′′]nickel(II) tetra­hydrate
title Crystal structure and Hirshfeld surface analysis of (succinato-κO)[N,N,N′,N′-tetra­kis­(2-hy­droxy­eth­yl)ethyl­enedi­amine-κ(5) O,N,N′,O′,O′′]nickel(II) tetra­hydrate
title_full Crystal structure and Hirshfeld surface analysis of (succinato-κO)[N,N,N′,N′-tetra­kis­(2-hy­droxy­eth­yl)ethyl­enedi­amine-κ(5) O,N,N′,O′,O′′]nickel(II) tetra­hydrate
title_fullStr Crystal structure and Hirshfeld surface analysis of (succinato-κO)[N,N,N′,N′-tetra­kis­(2-hy­droxy­eth­yl)ethyl­enedi­amine-κ(5) O,N,N′,O′,O′′]nickel(II) tetra­hydrate
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of (succinato-κO)[N,N,N′,N′-tetra­kis­(2-hy­droxy­eth­yl)ethyl­enedi­amine-κ(5) O,N,N′,O′,O′′]nickel(II) tetra­hydrate
title_short Crystal structure and Hirshfeld surface analysis of (succinato-κO)[N,N,N′,N′-tetra­kis­(2-hy­droxy­eth­yl)ethyl­enedi­amine-κ(5) O,N,N′,O′,O′′]nickel(II) tetra­hydrate
title_sort crystal structure and hirshfeld surface analysis of (succinato-κo)[n,n,n′,n′-tetra­kis­(2-hy­droxy­eth­yl)ethyl­enedi­amine-κ(5) o,n,n′,o′,o′′]nickel(ii) tetra­hydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6281127/
https://www.ncbi.nlm.nih.gov/pubmed/30574359
http://dx.doi.org/10.1107/S2056989018015359
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