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Oxygen Reduction Activity and Stability of Composite Pd(x)/Co-Nanofilms/C Electrocatalysts in Acid and Alkaline Media
The morphology tuning of Pd and Pd-M nanoparticles is one of the significant strategies to control the catalytic activity toward oxygen reduction reaction (ORR). In this study, composite Pdx/Co-nanofilms/C electrocatalysts of Pd nanoparticles implanted onto Co nanofilms were synthesized on an immisc...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Frontiers Media S.A.
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6281968/ https://www.ncbi.nlm.nih.gov/pubmed/30555821 http://dx.doi.org/10.3389/fchem.2018.00596 |
Sumario: | The morphology tuning of Pd and Pd-M nanoparticles is one of the significant strategies to control the catalytic activity toward oxygen reduction reaction (ORR). In this study, composite Pdx/Co-nanofilms/C electrocatalysts of Pd nanoparticles implanted onto Co nanofilms were synthesized on an immiscible ionic liquid (IL)/water interface for ORR. The Pd nanoparticles implanted onto Co nanofilms show a marked distortion of crystal lattice and surface roughness. These Pdx/Co-nanofilms/C electrocatalysts exhibit enhanced activity for ORR compared with Pd/C and PdxCo/C catalysts in both acid and alkaline solutions, in which the Pd3/Co-nanofilms/C catalyst displays the highest ORR mass activity. The superior ORR mass activities of the fabricated Pdx/Co-nanofilms/C catalysts may be mainly attributed to their larger catalytic areas, which are conferred by the rough surface of Pd nanoparticles with a distorted crystal lattice, and the synergistic effect between the surface Pd atoms and the 2D Co nanofilm substrate. The relationship between ORR mass activity and Pd/Co atom ratio varies in different electrolytes. Furthermore, by using proper heat-treatment methods, the Pdx/Co-nanofilms/C catalysts exhibit improved cycling stability compared with pure Pd/C catalyst after extended potential cycling. |
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