A Catalytic Cross‐Olefination of Diazo Compounds with Sulfoxonium Ylides

A ruthenium‐catalysed cross‐olefination of diazo compounds and sulfoxonium ylides is presented. Our reaction design exploits the intrinsic difference in reactivity of diazo compounds and sulfoxonium ylides as both carbene precursors and nucleophiles, which results in a highly selective reaction.

Detalles Bibliográficos
Autores principales: Neuhaus, James D., Bauer, Adriano, Pinto, Alexandre, Maulide, Nuno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6283242/
https://www.ncbi.nlm.nih.gov/pubmed/30264529
http://dx.doi.org/10.1002/anie.201809934

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6283242/
https://www.ncbi.nlm.nih.gov/pubmed/30264529
http://dx.doi.org/10.1002/anie.201809934

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