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Stibine-protected Au(13) nanoclusters: syntheses, properties and facile conversion to GSH-protected Au(25) nanocluster

Monostibine-protected ionic Au(13) nanoclusters, namely, [Au(13)(L)(8)(Cl)(4)][Cl] (L= SbPh(3), 2a·Cl; Sb(p-tolyl)(3), 2b·Cl) were prepared by the direct reduction of Au(L)Cl with NaBH(4) in dichloromethane. Anion exchange with 2a·Cl afforded [Au(13)(SbPh(3))(8)(Cl)(4)][X] (X = PF(6), 2a·PF(6); BPh(...

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Detalles Bibliográficos
Autores principales:	Li, Ying-Zhou, Ganguly, Rakesh, Hong, Kar Yiu, Li, Yongxin, Tessensohn, Malcolm Eugene, Webster, Richard, Leong, Weng Kee
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6289101/ https://www.ncbi.nlm.nih.gov/pubmed/30627392 http://dx.doi.org/10.1039/c8sc03132k

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