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Low-defectiveness exfoliation of MoS(2) nanoparticles and their embedment in hybrid light-emitting polymer nanofibers

Molybdenum disulfide (MoS(2)) has been attracting extraordinary attention for its intriguing optical, electronic and mechanical properties. Here, we demonstrate hybrid, organic–inorganic light-emitting nanofibers based on MoS(2) nanoparticle dopants obtained through a simple and inexpensive sonicati...

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Autores principales: Portone, Alberto, Romano, Luigi, Fasano, Vito, Di Corato, Riccardo, Camposeo, Andrea, Fabbri, Filippo, Cardarelli, Francesco, Pisignano, Dario, Persano, Luana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6289106/
https://www.ncbi.nlm.nih.gov/pubmed/30431042
http://dx.doi.org/10.1039/c8nr06294c
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author Portone, Alberto
Romano, Luigi
Fasano, Vito
Di Corato, Riccardo
Camposeo, Andrea
Fabbri, Filippo
Cardarelli, Francesco
Pisignano, Dario
Persano, Luana
author_facet Portone, Alberto
Romano, Luigi
Fasano, Vito
Di Corato, Riccardo
Camposeo, Andrea
Fabbri, Filippo
Cardarelli, Francesco
Pisignano, Dario
Persano, Luana
author_sort Portone, Alberto
collection PubMed
description Molybdenum disulfide (MoS(2)) has been attracting extraordinary attention for its intriguing optical, electronic and mechanical properties. Here, we demonstrate hybrid, organic–inorganic light-emitting nanofibers based on MoS(2) nanoparticle dopants obtained through a simple and inexpensive sonication process in N-methyl-2-pyrrolidone and successfully encapsulate the nanofibers in polymer filaments. The gentle exfoliation method used to produce the MoS(2) nanoparticles results in low defectiveness and preserves the stoichiometry. The fabricated hybrid fibers are smooth, uniform and flawless and exhibit bright and continuous light emission. Moreover, the fibers show significant capability for waveguiding self-emitted light along their longitudinal axes. These findings suggest that emissive MoS(2) fibers formed by gentle exfoliation are novel and highly promising optical materials for sensing surfaces and photonic circuits.
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spelling pubmed-62891062019-01-09 Low-defectiveness exfoliation of MoS(2) nanoparticles and their embedment in hybrid light-emitting polymer nanofibers Portone, Alberto Romano, Luigi Fasano, Vito Di Corato, Riccardo Camposeo, Andrea Fabbri, Filippo Cardarelli, Francesco Pisignano, Dario Persano, Luana Nanoscale Chemistry Molybdenum disulfide (MoS(2)) has been attracting extraordinary attention for its intriguing optical, electronic and mechanical properties. Here, we demonstrate hybrid, organic–inorganic light-emitting nanofibers based on MoS(2) nanoparticle dopants obtained through a simple and inexpensive sonication process in N-methyl-2-pyrrolidone and successfully encapsulate the nanofibers in polymer filaments. The gentle exfoliation method used to produce the MoS(2) nanoparticles results in low defectiveness and preserves the stoichiometry. The fabricated hybrid fibers are smooth, uniform and flawless and exhibit bright and continuous light emission. Moreover, the fibers show significant capability for waveguiding self-emitted light along their longitudinal axes. These findings suggest that emissive MoS(2) fibers formed by gentle exfoliation are novel and highly promising optical materials for sensing surfaces and photonic circuits. Royal Society of Chemistry 2018-12-14 2018-11-15 /pmc/articles/PMC6289106/ /pubmed/30431042 http://dx.doi.org/10.1039/c8nr06294c Text en This journal is © The Royal Society of Chemistry 2018 http://creativecommons.org/licenses/by-nc/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)
spellingShingle Chemistry
Portone, Alberto
Romano, Luigi
Fasano, Vito
Di Corato, Riccardo
Camposeo, Andrea
Fabbri, Filippo
Cardarelli, Francesco
Pisignano, Dario
Persano, Luana
Low-defectiveness exfoliation of MoS(2) nanoparticles and their embedment in hybrid light-emitting polymer nanofibers
title Low-defectiveness exfoliation of MoS(2) nanoparticles and their embedment in hybrid light-emitting polymer nanofibers
title_full Low-defectiveness exfoliation of MoS(2) nanoparticles and their embedment in hybrid light-emitting polymer nanofibers
title_fullStr Low-defectiveness exfoliation of MoS(2) nanoparticles and their embedment in hybrid light-emitting polymer nanofibers
title_full_unstemmed Low-defectiveness exfoliation of MoS(2) nanoparticles and their embedment in hybrid light-emitting polymer nanofibers
title_short Low-defectiveness exfoliation of MoS(2) nanoparticles and their embedment in hybrid light-emitting polymer nanofibers
title_sort low-defectiveness exfoliation of mos(2) nanoparticles and their embedment in hybrid light-emitting polymer nanofibers
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6289106/
https://www.ncbi.nlm.nih.gov/pubmed/30431042
http://dx.doi.org/10.1039/c8nr06294c
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