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Graphene catalyzes the reversible formation of a C–C bond between two molecules

Carbon deposits are well-known inhibitors of transition metal catalysts. In contrast to this undesirable behavior, here we show that epitaxial graphene grown on Ru(0001) promotes the reversible formation of a C–C bond between −CH(2)CN and 7,7,8,8-tetracyano-p-quinodimethane (TCNQ). The catalytic rol...

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Detalles Bibliográficos
Autores principales: Navarro, J. J., Pisarra, M., Nieto-Ortega, B., Villalva, J., Ayani, C. G., Díaz, C., Calleja, F., Miranda, R., Martín, F., Pérez, E. M., Vázquez de Parga, A. L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6294602/
https://www.ncbi.nlm.nih.gov/pubmed/30555920
http://dx.doi.org/10.1126/sciadv.aau9366