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Multicomponent metal–organic framework membranes for advanced functional composites
The diverse chemical and structural properties of metal–organic frameworks (MOFs) make them attractive for myriad applications, but their native powder form is limiting for industrial implementation. Composite materials of MOFs hold promise as a means of exploiting MOF properties in engineered forms...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6296215/ https://www.ncbi.nlm.nih.gov/pubmed/30627402 http://dx.doi.org/10.1039/c8sc02356e |
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author | Denny, Michael S. Kalaj, Mark Bentz, Kyle C. Cohen, Seth M. |
author_facet | Denny, Michael S. Kalaj, Mark Bentz, Kyle C. Cohen, Seth M. |
author_sort | Denny, Michael S. |
collection | PubMed |
description | The diverse chemical and structural properties of metal–organic frameworks (MOFs) make them attractive for myriad applications, but their native powder form is limiting for industrial implementation. Composite materials of MOFs hold promise as a means of exploiting MOF properties in engineered forms for real-world applications. While interest in MOF composites is growing, research to date has largely focused on utilization of single MOF systems. The vast number of different MOF structures provides ample opportunity to mix and match distinct MOF species in a single composite to prepare multifunctional systems. In this work, we describe the preparation of three types of multi-MOF composites with poly(vinylidene fluoride) (PVDF): (1) co-cast MOF MMMs, (2) mixed MOF MMMs, and (3) multilayer MOF MMMs. Finally, MOF MMMs are explored as catalytic membrane reactors for chemical transformations. |
format | Online Article Text |
id | pubmed-6296215 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-62962152019-01-09 Multicomponent metal–organic framework membranes for advanced functional composites Denny, Michael S. Kalaj, Mark Bentz, Kyle C. Cohen, Seth M. Chem Sci Chemistry The diverse chemical and structural properties of metal–organic frameworks (MOFs) make them attractive for myriad applications, but their native powder form is limiting for industrial implementation. Composite materials of MOFs hold promise as a means of exploiting MOF properties in engineered forms for real-world applications. While interest in MOF composites is growing, research to date has largely focused on utilization of single MOF systems. The vast number of different MOF structures provides ample opportunity to mix and match distinct MOF species in a single composite to prepare multifunctional systems. In this work, we describe the preparation of three types of multi-MOF composites with poly(vinylidene fluoride) (PVDF): (1) co-cast MOF MMMs, (2) mixed MOF MMMs, and (3) multilayer MOF MMMs. Finally, MOF MMMs are explored as catalytic membrane reactors for chemical transformations. Royal Society of Chemistry 2018-09-17 /pmc/articles/PMC6296215/ /pubmed/30627402 http://dx.doi.org/10.1039/c8sc02356e Text en This journal is © The Royal Society of Chemistry 2018 http://creativecommons.org/licenses/by-nc/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0) |
spellingShingle | Chemistry Denny, Michael S. Kalaj, Mark Bentz, Kyle C. Cohen, Seth M. Multicomponent metal–organic framework membranes for advanced functional composites |
title | Multicomponent metal–organic framework membranes for advanced functional composites
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title_full | Multicomponent metal–organic framework membranes for advanced functional composites
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title_fullStr | Multicomponent metal–organic framework membranes for advanced functional composites
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title_full_unstemmed | Multicomponent metal–organic framework membranes for advanced functional composites
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title_short | Multicomponent metal–organic framework membranes for advanced functional composites
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title_sort | multicomponent metal–organic framework membranes for advanced functional composites |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6296215/ https://www.ncbi.nlm.nih.gov/pubmed/30627402 http://dx.doi.org/10.1039/c8sc02356e |
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