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Multicomponent metal–organic framework membranes for advanced functional composites

The diverse chemical and structural properties of metal–organic frameworks (MOFs) make them attractive for myriad applications, but their native powder form is limiting for industrial implementation. Composite materials of MOFs hold promise as a means of exploiting MOF properties in engineered forms...

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Detalles Bibliográficos
Autores principales: Denny, Michael S., Kalaj, Mark, Bentz, Kyle C., Cohen, Seth M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6296215/
https://www.ncbi.nlm.nih.gov/pubmed/30627402
http://dx.doi.org/10.1039/c8sc02356e
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author Denny, Michael S.
Kalaj, Mark
Bentz, Kyle C.
Cohen, Seth M.
author_facet Denny, Michael S.
Kalaj, Mark
Bentz, Kyle C.
Cohen, Seth M.
author_sort Denny, Michael S.
collection PubMed
description The diverse chemical and structural properties of metal–organic frameworks (MOFs) make them attractive for myriad applications, but their native powder form is limiting for industrial implementation. Composite materials of MOFs hold promise as a means of exploiting MOF properties in engineered forms for real-world applications. While interest in MOF composites is growing, research to date has largely focused on utilization of single MOF systems. The vast number of different MOF structures provides ample opportunity to mix and match distinct MOF species in a single composite to prepare multifunctional systems. In this work, we describe the preparation of three types of multi-MOF composites with poly(vinylidene fluoride) (PVDF): (1) co-cast MOF MMMs, (2) mixed MOF MMMs, and (3) multilayer MOF MMMs. Finally, MOF MMMs are explored as catalytic membrane reactors for chemical transformations.
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spelling pubmed-62962152019-01-09 Multicomponent metal–organic framework membranes for advanced functional composites Denny, Michael S. Kalaj, Mark Bentz, Kyle C. Cohen, Seth M. Chem Sci Chemistry The diverse chemical and structural properties of metal–organic frameworks (MOFs) make them attractive for myriad applications, but their native powder form is limiting for industrial implementation. Composite materials of MOFs hold promise as a means of exploiting MOF properties in engineered forms for real-world applications. While interest in MOF composites is growing, research to date has largely focused on utilization of single MOF systems. The vast number of different MOF structures provides ample opportunity to mix and match distinct MOF species in a single composite to prepare multifunctional systems. In this work, we describe the preparation of three types of multi-MOF composites with poly(vinylidene fluoride) (PVDF): (1) co-cast MOF MMMs, (2) mixed MOF MMMs, and (3) multilayer MOF MMMs. Finally, MOF MMMs are explored as catalytic membrane reactors for chemical transformations. Royal Society of Chemistry 2018-09-17 /pmc/articles/PMC6296215/ /pubmed/30627402 http://dx.doi.org/10.1039/c8sc02356e Text en This journal is © The Royal Society of Chemistry 2018 http://creativecommons.org/licenses/by-nc/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)
spellingShingle Chemistry
Denny, Michael S.
Kalaj, Mark
Bentz, Kyle C.
Cohen, Seth M.
Multicomponent metal–organic framework membranes for advanced functional composites
title Multicomponent metal–organic framework membranes for advanced functional composites
title_full Multicomponent metal–organic framework membranes for advanced functional composites
title_fullStr Multicomponent metal–organic framework membranes for advanced functional composites
title_full_unstemmed Multicomponent metal–organic framework membranes for advanced functional composites
title_short Multicomponent metal–organic framework membranes for advanced functional composites
title_sort multicomponent metal–organic framework membranes for advanced functional composites
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6296215/
https://www.ncbi.nlm.nih.gov/pubmed/30627402
http://dx.doi.org/10.1039/c8sc02356e
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AT cohensethm multicomponentmetalorganicframeworkmembranesforadvancedfunctionalcomposites