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Degenerative xanthate transfer to olefins under visible-light photocatalysis
The degenerative transfer of xanthates to olefins is enabled by the iridium-based photocatalyst [Ir{dF(CF(3))ppy}(2)(dtbbpy)](PF(6)) under blue LED light irradiation. Detailed mechanistic investigations through kinetics and photophysical studies revealed that the process operates under a radical cha...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6296426/ https://www.ncbi.nlm.nih.gov/pubmed/30591827 http://dx.doi.org/10.3762/bjoc.14.283 |