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Linear Eyring Plots Conceal a Change in the Rate-Limiting Step in an Enzyme Reaction
[Image: see text] The temperature dependence of psychrophilic and mesophilic (R)-3-hydroxybutyrate dehydrogenase steady-state rates yields nonlinear and linear Eyring plots, respectively. Solvent viscosity effects and multiple- and single-turnover pre-steady-state kinetics demonstrate that while pro...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6300308/ https://www.ncbi.nlm.nih.gov/pubmed/30472832 http://dx.doi.org/10.1021/acs.biochem.8b01099 |