Unlocking a Diazirine Long-Lived Nuclear Singlet State via Photochemistry: NMR Detection and Lifetime of an Unstabilized Diazo-Compound

[Image: see text] Diazirines are important for photoaffinity labeling, and their photoisomerization is relatively well-known. This work shows how hyperpolarized NMR spectroscopy can be used to characterize an unstable diazo-compound formed via photoisomerization of a (15)N(2)-labeled silyl-ether-sub...

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Detalles Bibliográficos
Autores principales: Procacci, Barbara, Roy, Soumya S., Norcott, Philip, Turner, Norman, Duckett, Simon B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6300312/
https://www.ncbi.nlm.nih.gov/pubmed/30407809
http://dx.doi.org/10.1021/jacs.8b10923

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6300312/
https://www.ncbi.nlm.nih.gov/pubmed/30407809
http://dx.doi.org/10.1021/jacs.8b10923

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