Shape-selective crystallisation of fluxional carbon cages

Dynamic covalent rearrangements of fluxional carbon cages, such as bullvalenes and barbaralanes, impart ‘shapeshifting’ molecular properties. Here, a series of five barbaralanes each interconvert dynamically between two constitutional isomers in solution, but resolve to single isomers upon crystalli...

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Detalles Bibliográficos
Autores principales: Bismillah, Aisha N., Sturala, Jiri, Chapin, Brette M., Yufit, Dmitry S., Hodgkinson, Paul, McGonigal, Paul R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6301275/
https://www.ncbi.nlm.nih.gov/pubmed/30647882
http://dx.doi.org/10.1039/c8sc04303e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6301275/
https://www.ncbi.nlm.nih.gov/pubmed/30647882
http://dx.doi.org/10.1039/c8sc04303e

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