Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal–Organic Framework

[Image: see text] We report a record-high SO(2) adsorption capacity of 12.3 mmol g(–1) in a robust porous material, MFM-601, at 298 K and 1.0 bar. SO(2) adsorption in MFM-601 is fully reversible and highly selective over CO(2) and N(2). The binding domains for adsorbed SO(2) and CO(2) molecules in M...

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Autores principales: Carter, Joseph H., Han, Xue, Moreau, Florian Y., da Silva, Ivan, Nevin, Adam, Godfrey, Harry G. W., Tang, Chiu C., Yang, Sihai, Schröder, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6301759/
https://www.ncbi.nlm.nih.gov/pubmed/30418751
http://dx.doi.org/10.1021/jacs.8b08433
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author Carter, Joseph H.
Han, Xue
Moreau, Florian Y.
da Silva, Ivan
Nevin, Adam
Godfrey, Harry G. W.
Tang, Chiu C.
Yang, Sihai
Schröder, Martin
author_facet Carter, Joseph H.
Han, Xue
Moreau, Florian Y.
da Silva, Ivan
Nevin, Adam
Godfrey, Harry G. W.
Tang, Chiu C.
Yang, Sihai
Schröder, Martin
author_sort Carter, Joseph H.
collection PubMed
description [Image: see text] We report a record-high SO(2) adsorption capacity of 12.3 mmol g(–1) in a robust porous material, MFM-601, at 298 K and 1.0 bar. SO(2) adsorption in MFM-601 is fully reversible and highly selective over CO(2) and N(2). The binding domains for adsorbed SO(2) and CO(2) molecules in MFM-601 have been determined by in situ synchrotron X-ray diffraction experiments, giving insights at the molecular level to the basis of the observed high selectivity.
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spelling pubmed-63017592018-12-25 Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal–Organic Framework Carter, Joseph H. Han, Xue Moreau, Florian Y. da Silva, Ivan Nevin, Adam Godfrey, Harry G. W. Tang, Chiu C. Yang, Sihai Schröder, Martin J Am Chem Soc [Image: see text] We report a record-high SO(2) adsorption capacity of 12.3 mmol g(–1) in a robust porous material, MFM-601, at 298 K and 1.0 bar. SO(2) adsorption in MFM-601 is fully reversible and highly selective over CO(2) and N(2). The binding domains for adsorbed SO(2) and CO(2) molecules in MFM-601 have been determined by in situ synchrotron X-ray diffraction experiments, giving insights at the molecular level to the basis of the observed high selectivity. American Chemical Society 2018-11-12 2018-11-21 /pmc/articles/PMC6301759/ /pubmed/30418751 http://dx.doi.org/10.1021/jacs.8b08433 Text en Copyright © 2018 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Carter, Joseph H.
Han, Xue
Moreau, Florian Y.
da Silva, Ivan
Nevin, Adam
Godfrey, Harry G. W.
Tang, Chiu C.
Yang, Sihai
Schröder, Martin
Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal–Organic Framework
title Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal–Organic Framework
title_full Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal–Organic Framework
title_fullStr Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal–Organic Framework
title_full_unstemmed Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal–Organic Framework
title_short Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal–Organic Framework
title_sort exceptional adsorption and binding of sulfur dioxide in a robust zirconium-based metal–organic framework
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6301759/
https://www.ncbi.nlm.nih.gov/pubmed/30418751
http://dx.doi.org/10.1021/jacs.8b08433
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