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Highly sensitive two-dimensional MoS(2) gas sensor decorated with Pt nanoparticles

A two-dimensional molybdenum disulfide (MoS(2))-based gas sensor was decorated with Pt nanoparticles (NPs) for high sensitivity and low limit of detection (LOD) for specific gases (NH(3) and H(2)S). The two-dimensional MoS(2) film was grown at 400°C using metal organic gas vapour deposition. To fabr...

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Autores principales: Park, Jaeseo, Mun, Jihun, Shin, Jae-Soo, Kang, Sang-Woo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6304109/
https://www.ncbi.nlm.nih.gov/pubmed/30662750
http://dx.doi.org/10.1098/rsos.181462
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author Park, Jaeseo
Mun, Jihun
Shin, Jae-Soo
Kang, Sang-Woo
author_facet Park, Jaeseo
Mun, Jihun
Shin, Jae-Soo
Kang, Sang-Woo
author_sort Park, Jaeseo
collection PubMed
description A two-dimensional molybdenum disulfide (MoS(2))-based gas sensor was decorated with Pt nanoparticles (NPs) for high sensitivity and low limit of detection (LOD) for specific gases (NH(3) and H(2)S). The two-dimensional MoS(2) film was grown at 400°C using metal organic gas vapour deposition. To fabricate the MoS(2) gas sensor, an interdigitated Au/Ti electrode was deposited using the electron beam (e-beam) evaporation method with a stencil mask. The MoS(2) gas sensor without metal decoration sensitively detects NH(3) and H(2)S gas down to 2.5 and 30 ppm, respectively, at room temperature (RT). However, for improved detection of NH(3) and H(2)S gas, we investigated the functionalization strategy using metal decoration. Pt NP decoration modulated the electronic properties of MoS(2), significantly improving the sensitivity of NH(3) and H(2)S gas by 5.58× and 4.25×, respectively, compared with the undecorated MoS(2) gas sensor under concentrations of 70 ppm. Furthermore, the Pt NP-decorated MoS(2) sensor had lower LODs for NH(3) and H(2)S gas of 130 ppb and 5 ppm, respectively, at RT.
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spelling pubmed-63041092019-01-18 Highly sensitive two-dimensional MoS(2) gas sensor decorated with Pt nanoparticles Park, Jaeseo Mun, Jihun Shin, Jae-Soo Kang, Sang-Woo R Soc Open Sci Chemistry A two-dimensional molybdenum disulfide (MoS(2))-based gas sensor was decorated with Pt nanoparticles (NPs) for high sensitivity and low limit of detection (LOD) for specific gases (NH(3) and H(2)S). The two-dimensional MoS(2) film was grown at 400°C using metal organic gas vapour deposition. To fabricate the MoS(2) gas sensor, an interdigitated Au/Ti electrode was deposited using the electron beam (e-beam) evaporation method with a stencil mask. The MoS(2) gas sensor without metal decoration sensitively detects NH(3) and H(2)S gas down to 2.5 and 30 ppm, respectively, at room temperature (RT). However, for improved detection of NH(3) and H(2)S gas, we investigated the functionalization strategy using metal decoration. Pt NP decoration modulated the electronic properties of MoS(2), significantly improving the sensitivity of NH(3) and H(2)S gas by 5.58× and 4.25×, respectively, compared with the undecorated MoS(2) gas sensor under concentrations of 70 ppm. Furthermore, the Pt NP-decorated MoS(2) sensor had lower LODs for NH(3) and H(2)S gas of 130 ppb and 5 ppm, respectively, at RT. The Royal Society 2018-12-12 /pmc/articles/PMC6304109/ /pubmed/30662750 http://dx.doi.org/10.1098/rsos.181462 Text en © 2018 The Authors. http://creativecommons.org/licenses/by/4.0/ Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/, which permits unrestricted use, provided the original author and source are credited.
spellingShingle Chemistry
Park, Jaeseo
Mun, Jihun
Shin, Jae-Soo
Kang, Sang-Woo
Highly sensitive two-dimensional MoS(2) gas sensor decorated with Pt nanoparticles
title Highly sensitive two-dimensional MoS(2) gas sensor decorated with Pt nanoparticles
title_full Highly sensitive two-dimensional MoS(2) gas sensor decorated with Pt nanoparticles
title_fullStr Highly sensitive two-dimensional MoS(2) gas sensor decorated with Pt nanoparticles
title_full_unstemmed Highly sensitive two-dimensional MoS(2) gas sensor decorated with Pt nanoparticles
title_short Highly sensitive two-dimensional MoS(2) gas sensor decorated with Pt nanoparticles
title_sort highly sensitive two-dimensional mos(2) gas sensor decorated with pt nanoparticles
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6304109/
https://www.ncbi.nlm.nih.gov/pubmed/30662750
http://dx.doi.org/10.1098/rsos.181462
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