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Generalization of Prigogine’s theorem for the case of full differential of entropy
In this paper we propose a solution to the problem associated with the presence of an incomplete differential of entropy in Prigogine's theorem on the minimum of entropy production. A generalized theorem on the minimum rate of change of entropy near the stationary state of the system, which is...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6304459/ https://www.ncbi.nlm.nih.gov/pubmed/30591914 http://dx.doi.org/10.1016/j.mex.2018.11.009 |
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author | Shapovalov, V.I. Kazakov, N.V. |
author_facet | Shapovalov, V.I. Kazakov, N.V. |
author_sort | Shapovalov, V.I. |
collection | PubMed |
description | In this paper we propose a solution to the problem associated with the presence of an incomplete differential of entropy in Prigogine's theorem on the minimum of entropy production. A generalized theorem on the minimum rate of change of entropy near the stationary state of the system, which is under the influence of the entrostat, is formulated. It is shown that the mathematical expression of the generalized theorem contains the full differential of entropy. • Our new method consists in applying of the statistical criterion for the entropy change in an open system (SCEC) for analyzing the I. • Prigogine’s model in order to generalize the theorem on the minimum entropy production for the case of the total differential of entropy. |
format | Online Article Text |
id | pubmed-6304459 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | Elsevier |
record_format | MEDLINE/PubMed |
spelling | pubmed-63044592018-12-27 Generalization of Prigogine’s theorem for the case of full differential of entropy Shapovalov, V.I. Kazakov, N.V. MethodsX Physics and Astronomy In this paper we propose a solution to the problem associated with the presence of an incomplete differential of entropy in Prigogine's theorem on the minimum of entropy production. A generalized theorem on the minimum rate of change of entropy near the stationary state of the system, which is under the influence of the entrostat, is formulated. It is shown that the mathematical expression of the generalized theorem contains the full differential of entropy. • Our new method consists in applying of the statistical criterion for the entropy change in an open system (SCEC) for analyzing the I. • Prigogine’s model in order to generalize the theorem on the minimum entropy production for the case of the total differential of entropy. Elsevier 2018-11-20 /pmc/articles/PMC6304459/ /pubmed/30591914 http://dx.doi.org/10.1016/j.mex.2018.11.009 Text en © 2018 The Author(s) http://creativecommons.org/licenses/by/4.0/ This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Physics and Astronomy Shapovalov, V.I. Kazakov, N.V. Generalization of Prigogine’s theorem for the case of full differential of entropy |
title | Generalization of Prigogine’s theorem for the case of full differential of entropy |
title_full | Generalization of Prigogine’s theorem for the case of full differential of entropy |
title_fullStr | Generalization of Prigogine’s theorem for the case of full differential of entropy |
title_full_unstemmed | Generalization of Prigogine’s theorem for the case of full differential of entropy |
title_short | Generalization of Prigogine’s theorem for the case of full differential of entropy |
title_sort | generalization of prigogine’s theorem for the case of full differential of entropy |
topic | Physics and Astronomy |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6304459/ https://www.ncbi.nlm.nih.gov/pubmed/30591914 http://dx.doi.org/10.1016/j.mex.2018.11.009 |
work_keys_str_mv | AT shapovalovvi generalizationofprigoginestheoremforthecaseoffulldifferentialofentropy AT kazakovnv generalizationofprigoginestheoremforthecaseoffulldifferentialofentropy |