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Generalization of Prigogine’s theorem for the case of full differential of entropy

In this paper we propose a solution to the problem associated with the presence of an incomplete differential of entropy in Prigogine's theorem on the minimum of entropy production. A generalized theorem on the minimum rate of change of entropy near the stationary state of the system, which is...

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Detalles Bibliográficos
Autores principales: Shapovalov, V.I., Kazakov, N.V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6304459/
https://www.ncbi.nlm.nih.gov/pubmed/30591914
http://dx.doi.org/10.1016/j.mex.2018.11.009
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author Shapovalov, V.I.
Kazakov, N.V.
author_facet Shapovalov, V.I.
Kazakov, N.V.
author_sort Shapovalov, V.I.
collection PubMed
description In this paper we propose a solution to the problem associated with the presence of an incomplete differential of entropy in Prigogine's theorem on the minimum of entropy production. A generalized theorem on the minimum rate of change of entropy near the stationary state of the system, which is under the influence of the entrostat, is formulated. It is shown that the mathematical expression of the generalized theorem contains the full differential of entropy. • Our new method consists in applying of the statistical criterion for the entropy change in an open system (SCEC) for analyzing the I. • Prigogine’s model in order to generalize the theorem on the minimum entropy production for the case of the total differential of entropy.
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spelling pubmed-63044592018-12-27 Generalization of Prigogine’s theorem for the case of full differential of entropy Shapovalov, V.I. Kazakov, N.V. MethodsX Physics and Astronomy In this paper we propose a solution to the problem associated with the presence of an incomplete differential of entropy in Prigogine's theorem on the minimum of entropy production. A generalized theorem on the minimum rate of change of entropy near the stationary state of the system, which is under the influence of the entrostat, is formulated. It is shown that the mathematical expression of the generalized theorem contains the full differential of entropy. • Our new method consists in applying of the statistical criterion for the entropy change in an open system (SCEC) for analyzing the I. • Prigogine’s model in order to generalize the theorem on the minimum entropy production for the case of the total differential of entropy. Elsevier 2018-11-20 /pmc/articles/PMC6304459/ /pubmed/30591914 http://dx.doi.org/10.1016/j.mex.2018.11.009 Text en © 2018 The Author(s) http://creativecommons.org/licenses/by/4.0/ This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Physics and Astronomy
Shapovalov, V.I.
Kazakov, N.V.
Generalization of Prigogine’s theorem for the case of full differential of entropy
title Generalization of Prigogine’s theorem for the case of full differential of entropy
title_full Generalization of Prigogine’s theorem for the case of full differential of entropy
title_fullStr Generalization of Prigogine’s theorem for the case of full differential of entropy
title_full_unstemmed Generalization of Prigogine’s theorem for the case of full differential of entropy
title_short Generalization of Prigogine’s theorem for the case of full differential of entropy
title_sort generalization of prigogine’s theorem for the case of full differential of entropy
topic Physics and Astronomy
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6304459/
https://www.ncbi.nlm.nih.gov/pubmed/30591914
http://dx.doi.org/10.1016/j.mex.2018.11.009
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