Intramolecular Metal Exchange Reaction Promoted by Thiol Ligands

The synthesis of an alloy nanocluster that is atomically precise is the key to understanding the metal synergy effect at the atomic level. Using the Ag(2)Au(25)(SR)(18) nanocluster as a model, we reported a third approach for the metal exchange reaction, that is, intramolecular metal exchange. The s...

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Detalles Bibliográficos
Autores principales: Li, Yangfeng, Chen, Man, Wang, Shuxin, Zhu, Manzhou
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6316370/
https://www.ncbi.nlm.nih.gov/pubmed/30572582
http://dx.doi.org/10.3390/nano8121070
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author Li, Yangfeng
Chen, Man
Wang, Shuxin
Zhu, Manzhou
author_facet Li, Yangfeng
Chen, Man
Wang, Shuxin
Zhu, Manzhou
author_sort Li, Yangfeng
collection PubMed
description The synthesis of an alloy nanocluster that is atomically precise is the key to understanding the metal synergy effect at the atomic level. Using the Ag(2)Au(25)(SR)(18) nanocluster as a model, we reported a third approach for the metal exchange reaction, that is, intramolecular metal exchange. The surface adsorbed metal ions (i.e., Ag) can be exchanged with the kernel metal atoms (i.e., Au) that are promoted by thiol ligands. The exchanged gold atoms can be further stripped by the thiol ligands, and produce the Ag(x)Au(25−x)(SR)(18)(−) nanocluster.
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spelling pubmed-63163702019-01-10 Intramolecular Metal Exchange Reaction Promoted by Thiol Ligands Li, Yangfeng Chen, Man Wang, Shuxin Zhu, Manzhou Nanomaterials (Basel) Communication The synthesis of an alloy nanocluster that is atomically precise is the key to understanding the metal synergy effect at the atomic level. Using the Ag(2)Au(25)(SR)(18) nanocluster as a model, we reported a third approach for the metal exchange reaction, that is, intramolecular metal exchange. The surface adsorbed metal ions (i.e., Ag) can be exchanged with the kernel metal atoms (i.e., Au) that are promoted by thiol ligands. The exchanged gold atoms can be further stripped by the thiol ligands, and produce the Ag(x)Au(25−x)(SR)(18)(−) nanocluster. MDPI 2018-12-19 /pmc/articles/PMC6316370/ /pubmed/30572582 http://dx.doi.org/10.3390/nano8121070 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Li, Yangfeng
Chen, Man
Wang, Shuxin
Zhu, Manzhou
Intramolecular Metal Exchange Reaction Promoted by Thiol Ligands
title Intramolecular Metal Exchange Reaction Promoted by Thiol Ligands
title_full Intramolecular Metal Exchange Reaction Promoted by Thiol Ligands
title_fullStr Intramolecular Metal Exchange Reaction Promoted by Thiol Ligands
title_full_unstemmed Intramolecular Metal Exchange Reaction Promoted by Thiol Ligands
title_short Intramolecular Metal Exchange Reaction Promoted by Thiol Ligands
title_sort intramolecular metal exchange reaction promoted by thiol ligands
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6316370/
https://www.ncbi.nlm.nih.gov/pubmed/30572582
http://dx.doi.org/10.3390/nano8121070
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AT chenman intramolecularmetalexchangereactionpromotedbythiolligands
AT wangshuxin intramolecularmetalexchangereactionpromotedbythiolligands
AT zhumanzhou intramolecularmetalexchangereactionpromotedbythiolligands

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