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A convenient and practical synthesis of β-diketones bearing linear perfluorinated alkyl groups and a 2-thienyl moiety
A versatile and robust synthetic protocol for the preparation of β-diketones bearing 2-thienyl and perfluorinated alkyl radicals of different length or a methyl group was developed. This protocol is suitable for the preparation of multigram quantities of diketones without cumbersome purification pro...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Beilstein-Institut
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6317410/ https://www.ncbi.nlm.nih.gov/pubmed/30643588 http://dx.doi.org/10.3762/bjoc.14.290 |
| _version_ | 1783384740834836480 |
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| author | Taydakov, Ilya V Kreshchenova, Yuliya M Dolotova, Ekaterina P |
| author_facet | Taydakov, Ilya V Kreshchenova, Yuliya M Dolotova, Ekaterina P |
| author_sort | Taydakov, Ilya V |
| collection | PubMed |
| description | A versatile and robust synthetic protocol for the preparation of β-diketones bearing 2-thienyl and perfluorinated alkyl radicals of different length or a methyl group was developed. This protocol is suitable for the preparation of multigram quantities of diketones without cumbersome purification procedures. Moreover, the known method for purification of diketones via copper chelates was improved considerably. |
| format | Online Article Text |
| id | pubmed-6317410 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2018 |
| publisher | Beilstein-Institut |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-63174102019-01-14 A convenient and practical synthesis of β-diketones bearing linear perfluorinated alkyl groups and a 2-thienyl moiety Taydakov, Ilya V Kreshchenova, Yuliya M Dolotova, Ekaterina P Beilstein J Org Chem Full Research Paper A versatile and robust synthetic protocol for the preparation of β-diketones bearing 2-thienyl and perfluorinated alkyl radicals of different length or a methyl group was developed. This protocol is suitable for the preparation of multigram quantities of diketones without cumbersome purification procedures. Moreover, the known method for purification of diketones via copper chelates was improved considerably. Beilstein-Institut 2018-12-27 /pmc/articles/PMC6317410/ /pubmed/30643588 http://dx.doi.org/10.3762/bjoc.14.290 Text en Copyright © 2018, Taydakov et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
| spellingShingle | Full Research Paper Taydakov, Ilya V Kreshchenova, Yuliya M Dolotova, Ekaterina P A convenient and practical synthesis of β-diketones bearing linear perfluorinated alkyl groups and a 2-thienyl moiety |
| title | A convenient and practical synthesis of β-diketones bearing linear perfluorinated alkyl groups and a 2-thienyl moiety |
| title_full | A convenient and practical synthesis of β-diketones bearing linear perfluorinated alkyl groups and a 2-thienyl moiety |
| title_fullStr | A convenient and practical synthesis of β-diketones bearing linear perfluorinated alkyl groups and a 2-thienyl moiety |
| title_full_unstemmed | A convenient and practical synthesis of β-diketones bearing linear perfluorinated alkyl groups and a 2-thienyl moiety |
| title_short | A convenient and practical synthesis of β-diketones bearing linear perfluorinated alkyl groups and a 2-thienyl moiety |
| title_sort | convenient and practical synthesis of β-diketones bearing linear perfluorinated alkyl groups and a 2-thienyl moiety |
| topic | Full Research Paper |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6317410/ https://www.ncbi.nlm.nih.gov/pubmed/30643588 http://dx.doi.org/10.3762/bjoc.14.290 |
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