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Synthesis and characterization of TADDOL-based chiral group six PNP pincer tricarbonyl complexes
ABSTRACT: The new chiral PNP pincer ligand N(2),N(6)-bis((3aR, 8aR)-2,2-dimethyl-4,4,8,8-tetraphenyltetrahydro[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)pyridine-2,6-diamine (PNP-TADDOL) was synthesized in 80% isolated yield. Complexes of the type [M(PNP-TADDOL)(CO)(3)] (M = Cr, Mo, and W) were...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Springer Vienna
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6320742/ https://www.ncbi.nlm.nih.gov/pubmed/30662092 http://dx.doi.org/10.1007/s00706-018-2281-0 |