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Synthesis and characterization of bis- and tris-carbonyl Mn(I) and Re(I) PNP pincer complexes
ABSTRACT: A series of neutral bis- and cationic tris-carbonyl complexes of the types cis-[M(κ(3)P,N,P-PNP)(CO)(2)Y] and [M(κ(3)P,N,P-PNP)(CO)(3)](+) was prepared by reacting [M(CO)(5)Y] (M = Mn, Re; Y = Cl or Br) with PNP pincer ligands derived from the 2,6-diaminopyridine, 2,6-dihydroxypyridine, an...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Springer Vienna
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6320747/ https://www.ncbi.nlm.nih.gov/pubmed/30662093 http://dx.doi.org/10.1007/s00706-018-2307-7 |