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Formation of persistent organic diradicals from N,N′-diphenyl-3,7-diazacyclooctanes
ABSTRACT: N,N′-Diphenyl-3,7-diazacyclooctane and structurally related N,N′-diphenylbispidine derivatives react with silver(I) ions in a high-yielding C–C coupling reaction to produce dication–diradical species, with the silver ions serving a double function both as template and as an oxidant. The re...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Springer Vienna
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6320754/ https://www.ncbi.nlm.nih.gov/pubmed/30679878 http://dx.doi.org/10.1007/s00706-018-2298-4 |