Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B(12)H(11)NH(3)](−)

The synthesis and structural characterization of new derivatives of [B(12)H(12)](2−) is of fundamental interest and is expected to allow for extended applications. Herein we report on the synthesis of a series of amidine, amide, urea and isocyanate derivatives based on the amino-closo-dodecaborate a...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Yuanbin, Sun, Yuji, Wang, Tao, Liu, Jiyong, Spingler, Bernhard, Duttwyler, Simon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6321512/
https://www.ncbi.nlm.nih.gov/pubmed/30501105
http://dx.doi.org/10.3390/molecules23123137
_version_ 1783385460127563776
author Zhang, Yuanbin
Sun, Yuji
Wang, Tao
Liu, Jiyong
Spingler, Bernhard
Duttwyler, Simon
author_facet Zhang, Yuanbin
Sun, Yuji
Wang, Tao
Liu, Jiyong
Spingler, Bernhard
Duttwyler, Simon
author_sort Zhang, Yuanbin
collection PubMed
description The synthesis and structural characterization of new derivatives of [B(12)H(12)](2−) is of fundamental interest and is expected to allow for extended applications. Herein we report on the synthesis of a series of amidine, amide, urea and isocyanate derivatives based on the amino-closo-dodecaborate anion [B(12)H(11)NH(3)](−). Their structures have been confirmed by spectroscopic methods, and nine crystal structures are presented.
format Online
Article
Text
id pubmed-6321512
institution National Center for Biotechnology Information
language English
publishDate 2018
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-63215122019-01-14 Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B(12)H(11)NH(3)](−) Zhang, Yuanbin Sun, Yuji Wang, Tao Liu, Jiyong Spingler, Bernhard Duttwyler, Simon Molecules Article The synthesis and structural characterization of new derivatives of [B(12)H(12)](2−) is of fundamental interest and is expected to allow for extended applications. Herein we report on the synthesis of a series of amidine, amide, urea and isocyanate derivatives based on the amino-closo-dodecaborate anion [B(12)H(11)NH(3)](−). Their structures have been confirmed by spectroscopic methods, and nine crystal structures are presented. MDPI 2018-11-29 /pmc/articles/PMC6321512/ /pubmed/30501105 http://dx.doi.org/10.3390/molecules23123137 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zhang, Yuanbin
Sun, Yuji
Wang, Tao
Liu, Jiyong
Spingler, Bernhard
Duttwyler, Simon
Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B(12)H(11)NH(3)](−)
title Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B(12)H(11)NH(3)](−)
title_full Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B(12)H(11)NH(3)](−)
title_fullStr Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B(12)H(11)NH(3)](−)
title_full_unstemmed Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B(12)H(11)NH(3)](−)
title_short Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B(12)H(11)NH(3)](−)
title_sort synthesis and structural characterization of amidine, amide, urea and isocyanate derivatives of the amino-closo-dodecaborate anion [b(12)h(11)nh(3)](−)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6321512/
https://www.ncbi.nlm.nih.gov/pubmed/30501105
http://dx.doi.org/10.3390/molecules23123137
work_keys_str_mv AT zhangyuanbin synthesisandstructuralcharacterizationofamidineamideureaandisocyanatederivativesoftheaminoclosododecaborateanionb12h11nh3
AT sunyuji synthesisandstructuralcharacterizationofamidineamideureaandisocyanatederivativesoftheaminoclosododecaborateanionb12h11nh3
AT wangtao synthesisandstructuralcharacterizationofamidineamideureaandisocyanatederivativesoftheaminoclosododecaborateanionb12h11nh3
AT liujiyong synthesisandstructuralcharacterizationofamidineamideureaandisocyanatederivativesoftheaminoclosododecaborateanionb12h11nh3
AT spinglerbernhard synthesisandstructuralcharacterizationofamidineamideureaandisocyanatederivativesoftheaminoclosododecaborateanionb12h11nh3
AT duttwylersimon synthesisandstructuralcharacterizationofamidineamideureaandisocyanatederivativesoftheaminoclosododecaborateanionb12h11nh3

Ejemplares similares