Enhanced measurement of residual chemical shift anisotropy for small molecule structure elucidation

A method is introduced to measure residual chemical shift anisotropies conveniently and accurately in the mesophase of poly-γ-(benzyl-(L)-glutamate). The alignment amplitude is substantially enhanced over common methods which greatly benefits measurements particularly on sp(3) carbons. The approach...

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Detalles Bibliográficos
Autores principales: Liu, Yizhou, Cohen, Ryan D., Gustafson, Kirk R., Martin, Gary E., Williamson, R. Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6322199/
https://www.ncbi.nlm.nih.gov/pubmed/29505044
http://dx.doi.org/10.1039/c8cc00552d
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author Liu, Yizhou
Cohen, Ryan D.
Gustafson, Kirk R.
Martin, Gary E.
Williamson, R. Thomas
author_facet Liu, Yizhou
Cohen, Ryan D.
Gustafson, Kirk R.
Martin, Gary E.
Williamson, R. Thomas
author_sort Liu, Yizhou
collection PubMed
description A method is introduced to measure residual chemical shift anisotropies conveniently and accurately in the mesophase of poly-γ-(benzyl-(L)-glutamate). The alignment amplitude is substantially enhanced over common methods which greatly benefits measurements particularly on sp(3) carbons. The approach offers significant improvements in data accuracy and utility for small molecule structure determination.
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spelling pubmed-63221992019-01-07 Enhanced measurement of residual chemical shift anisotropy for small molecule structure elucidation Liu, Yizhou Cohen, Ryan D. Gustafson, Kirk R. Martin, Gary E. Williamson, R. Thomas Chem Commun (Camb) Article A method is introduced to measure residual chemical shift anisotropies conveniently and accurately in the mesophase of poly-γ-(benzyl-(L)-glutamate). The alignment amplitude is substantially enhanced over common methods which greatly benefits measurements particularly on sp(3) carbons. The approach offers significant improvements in data accuracy and utility for small molecule structure determination. 2018-04-24 /pmc/articles/PMC6322199/ /pubmed/29505044 http://dx.doi.org/10.1039/c8cc00552d Text en http://creativecommons.org/licenses/by/4.0/ This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
spellingShingle Article
Liu, Yizhou
Cohen, Ryan D.
Gustafson, Kirk R.
Martin, Gary E.
Williamson, R. Thomas
Enhanced measurement of residual chemical shift anisotropy for small molecule structure elucidation
title Enhanced measurement of residual chemical shift anisotropy for small molecule structure elucidation
title_full Enhanced measurement of residual chemical shift anisotropy for small molecule structure elucidation
title_fullStr Enhanced measurement of residual chemical shift anisotropy for small molecule structure elucidation
title_full_unstemmed Enhanced measurement of residual chemical shift anisotropy for small molecule structure elucidation
title_short Enhanced measurement of residual chemical shift anisotropy for small molecule structure elucidation
title_sort enhanced measurement of residual chemical shift anisotropy for small molecule structure elucidation
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6322199/
https://www.ncbi.nlm.nih.gov/pubmed/29505044
http://dx.doi.org/10.1039/c8cc00552d
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