Cargando…
Cover Feature: Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold (ChemistryOpen 1/2019)
The Cover Feature shows how coinage metals such as gold, silver, and copper are rapidly dissolved under mild and safe conditions by the ionic liquid 1‐hexyl‐3‐methylimidiazolim dibromoiodide ([C(6)C(1)Im][Br(2)I]), forming metal(I)–dibromo anionic complexes together with molecular iodine, as proven...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2018
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6323579/ http://dx.doi.org/10.1002/open.201800272 |
_version_ | 1783385795479994368 |
---|---|
author | May, Benjamin Lexow, Matthias Taccardi, Nicola Steinrück, Hans‐Peter Maier, Florian |
author_facet | May, Benjamin Lexow, Matthias Taccardi, Nicola Steinrück, Hans‐Peter Maier, Florian |
author_sort | May, Benjamin |
collection | PubMed |
description | The Cover Feature shows how coinage metals such as gold, silver, and copper are rapidly dissolved under mild and safe conditions by the ionic liquid 1‐hexyl‐3‐methylimidiazolim dibromoiodide ([C(6)C(1)Im][Br(2)I]), forming metal(I)–dibromo anionic complexes together with molecular iodine, as proven by X‐ray photoelectron spectroscopy, etching experiments, and gas‐phase analysis. Trihalide ionic liquids are shown to be promising candidates for precious‐metal etching and leaching media, and may also open new possibilities for Au(I) catalysis. More information can be found in the Full Paper by F. Maier and co‐workers on page 15 in Issue 1, 2019 (DOI: 10.1002/open.201800149).[Image: see text] |
format | Online Article Text |
id | pubmed-6323579 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-63235792019-01-10 Cover Feature: Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold (ChemistryOpen 1/2019) May, Benjamin Lexow, Matthias Taccardi, Nicola Steinrück, Hans‐Peter Maier, Florian ChemistryOpen Cover Pictures The Cover Feature shows how coinage metals such as gold, silver, and copper are rapidly dissolved under mild and safe conditions by the ionic liquid 1‐hexyl‐3‐methylimidiazolim dibromoiodide ([C(6)C(1)Im][Br(2)I]), forming metal(I)–dibromo anionic complexes together with molecular iodine, as proven by X‐ray photoelectron spectroscopy, etching experiments, and gas‐phase analysis. Trihalide ionic liquids are shown to be promising candidates for precious‐metal etching and leaching media, and may also open new possibilities for Au(I) catalysis. More information can be found in the Full Paper by F. Maier and co‐workers on page 15 in Issue 1, 2019 (DOI: 10.1002/open.201800149).[Image: see text] John Wiley and Sons Inc. 2018-11-30 /pmc/articles/PMC6323579/ http://dx.doi.org/10.1002/open.201800272 Text en © 2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim |
spellingShingle | Cover Pictures May, Benjamin Lexow, Matthias Taccardi, Nicola Steinrück, Hans‐Peter Maier, Florian Cover Feature: Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold (ChemistryOpen 1/2019) |
title | Cover Feature: Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold (ChemistryOpen 1/2019) |
title_full | Cover Feature: Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold (ChemistryOpen 1/2019) |
title_fullStr | Cover Feature: Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold (ChemistryOpen 1/2019) |
title_full_unstemmed | Cover Feature: Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold (ChemistryOpen 1/2019) |
title_short | Cover Feature: Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold (ChemistryOpen 1/2019) |
title_sort | cover feature: reactions of a polyhalide ionic liquid with copper, silver, and gold (chemistryopen 1/2019) |
topic | Cover Pictures |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6323579/ http://dx.doi.org/10.1002/open.201800272 |
work_keys_str_mv | AT maybenjamin coverfeaturereactionsofapolyhalideionicliquidwithcoppersilverandgoldchemistryopen12019 AT lexowmatthias coverfeaturereactionsofapolyhalideionicliquidwithcoppersilverandgoldchemistryopen12019 AT taccardinicola coverfeaturereactionsofapolyhalideionicliquidwithcoppersilverandgoldchemistryopen12019 AT steinruckhanspeter coverfeaturereactionsofapolyhalideionicliquidwithcoppersilverandgoldchemistryopen12019 AT maierflorian coverfeaturereactionsofapolyhalideionicliquidwithcoppersilverandgoldchemistryopen12019 |