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Cover Feature: Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold (ChemistryOpen 1/2019)

The Cover Feature shows how coinage metals such as gold, silver, and copper are rapidly dissolved under mild and safe conditions by the ionic liquid 1‐hexyl‐3‐methylimidiazolim dibromoiodide ([C(6)C(1)Im][Br(2)I]), forming metal(I)–dibromo anionic complexes together with molecular iodine, as proven...

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Detalles Bibliográficos
Autores principales: May, Benjamin, Lexow, Matthias, Taccardi, Nicola, Steinrück, Hans‐Peter, Maier, Florian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6323579/
http://dx.doi.org/10.1002/open.201800272
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author May, Benjamin
Lexow, Matthias
Taccardi, Nicola
Steinrück, Hans‐Peter
Maier, Florian
author_facet May, Benjamin
Lexow, Matthias
Taccardi, Nicola
Steinrück, Hans‐Peter
Maier, Florian
author_sort May, Benjamin
collection PubMed
description The Cover Feature shows how coinage metals such as gold, silver, and copper are rapidly dissolved under mild and safe conditions by the ionic liquid 1‐hexyl‐3‐methylimidiazolim dibromoiodide ([C(6)C(1)Im][Br(2)I]), forming metal(I)–dibromo anionic complexes together with molecular iodine, as proven by X‐ray photoelectron spectroscopy, etching experiments, and gas‐phase analysis. Trihalide ionic liquids are shown to be promising candidates for precious‐metal etching and leaching media, and may also open new possibilities for Au(I) catalysis. More information can be found in the Full Paper by F. Maier and co‐workers on page 15 in Issue 1, 2019 (DOI: 10.1002/open.201800149).[Image: see text]
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spelling pubmed-63235792019-01-10 Cover Feature: Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold (ChemistryOpen 1/2019) May, Benjamin Lexow, Matthias Taccardi, Nicola Steinrück, Hans‐Peter Maier, Florian ChemistryOpen Cover Pictures The Cover Feature shows how coinage metals such as gold, silver, and copper are rapidly dissolved under mild and safe conditions by the ionic liquid 1‐hexyl‐3‐methylimidiazolim dibromoiodide ([C(6)C(1)Im][Br(2)I]), forming metal(I)–dibromo anionic complexes together with molecular iodine, as proven by X‐ray photoelectron spectroscopy, etching experiments, and gas‐phase analysis. Trihalide ionic liquids are shown to be promising candidates for precious‐metal etching and leaching media, and may also open new possibilities for Au(I) catalysis. More information can be found in the Full Paper by F. Maier and co‐workers on page 15 in Issue 1, 2019 (DOI: 10.1002/open.201800149).[Image: see text] John Wiley and Sons Inc. 2018-11-30 /pmc/articles/PMC6323579/ http://dx.doi.org/10.1002/open.201800272 Text en © 2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
spellingShingle Cover Pictures
May, Benjamin
Lexow, Matthias
Taccardi, Nicola
Steinrück, Hans‐Peter
Maier, Florian
Cover Feature: Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold (ChemistryOpen 1/2019)
title Cover Feature: Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold (ChemistryOpen 1/2019)
title_full Cover Feature: Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold (ChemistryOpen 1/2019)
title_fullStr Cover Feature: Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold (ChemistryOpen 1/2019)
title_full_unstemmed Cover Feature: Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold (ChemistryOpen 1/2019)
title_short Cover Feature: Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold (ChemistryOpen 1/2019)
title_sort cover feature: reactions of a polyhalide ionic liquid with copper, silver, and gold (chemistryopen 1/2019)
topic Cover Pictures
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6323579/
http://dx.doi.org/10.1002/open.201800272
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