Cargando…

One-Step Generation of Reactive Superhydrophobic Surfaces via SiHCl(3)-Based Silicone Nanofilaments

[Image: see text] Superhydrophobic surfaces gain ever-growing attention because of their applicability in many (consumer) products/materials as they often display, among others, antifouling, anti-icing, and/or self-cleaning properties. A simple way to achieve superhydrophobicity is through the growt...

Descripción completa

Detalles Bibliográficos
Autores principales: Slagman, Sjoerd, Pujari, Sidharam P., Franssen, Maurice C. R., Zuilhof, Han
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6328287/
https://www.ncbi.nlm.nih.gov/pubmed/30395470
http://dx.doi.org/10.1021/acs.langmuir.8b02247
_version_ 1783386627237740544
author Slagman, Sjoerd
Pujari, Sidharam P.
Franssen, Maurice C. R.
Zuilhof, Han
author_facet Slagman, Sjoerd
Pujari, Sidharam P.
Franssen, Maurice C. R.
Zuilhof, Han
author_sort Slagman, Sjoerd
collection PubMed
description [Image: see text] Superhydrophobic surfaces gain ever-growing attention because of their applicability in many (consumer) products/materials as they often display, among others, antifouling, anti-icing, and/or self-cleaning properties. A simple way to achieve superhydrophobicity is through the growth of silicone nanofilaments. These nanofilaments, however, are very often nonreactive and thus difficult to utilize in subsequent chemistries. In response, we have developed a single-step procedure to grow (SiHCl(3)-based) silicone nanofilaments with selective reactivity that are intrinsically superhydrophobic. The silicone nanofilaments could be further functionalized via Pt-catalyzed hydrosilylation of exposed Si–H moieties. These surfaces are easily obtained using mild conditions and are stable under hydrolytic conditions (neutral water, 24 h at 80 °C) while remaining highly transparent, which makes them well suited for optical and photochemical experiments.
format Online
Article
Text
id pubmed-6328287
institution National Center for Biotechnology Information
language English
publishDate 2018
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-63282872019-01-17 One-Step Generation of Reactive Superhydrophobic Surfaces via SiHCl(3)-Based Silicone Nanofilaments Slagman, Sjoerd Pujari, Sidharam P. Franssen, Maurice C. R. Zuilhof, Han Langmuir [Image: see text] Superhydrophobic surfaces gain ever-growing attention because of their applicability in many (consumer) products/materials as they often display, among others, antifouling, anti-icing, and/or self-cleaning properties. A simple way to achieve superhydrophobicity is through the growth of silicone nanofilaments. These nanofilaments, however, are very often nonreactive and thus difficult to utilize in subsequent chemistries. In response, we have developed a single-step procedure to grow (SiHCl(3)-based) silicone nanofilaments with selective reactivity that are intrinsically superhydrophobic. The silicone nanofilaments could be further functionalized via Pt-catalyzed hydrosilylation of exposed Si–H moieties. These surfaces are easily obtained using mild conditions and are stable under hydrolytic conditions (neutral water, 24 h at 80 °C) while remaining highly transparent, which makes them well suited for optical and photochemical experiments. American Chemical Society 2018-11-05 2018-11-13 /pmc/articles/PMC6328287/ /pubmed/30395470 http://dx.doi.org/10.1021/acs.langmuir.8b02247 Text en Copyright © 2018 American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.
spellingShingle Slagman, Sjoerd
Pujari, Sidharam P.
Franssen, Maurice C. R.
Zuilhof, Han
One-Step Generation of Reactive Superhydrophobic Surfaces via SiHCl(3)-Based Silicone Nanofilaments
title One-Step Generation of Reactive Superhydrophobic Surfaces via SiHCl(3)-Based Silicone Nanofilaments
title_full One-Step Generation of Reactive Superhydrophobic Surfaces via SiHCl(3)-Based Silicone Nanofilaments
title_fullStr One-Step Generation of Reactive Superhydrophobic Surfaces via SiHCl(3)-Based Silicone Nanofilaments
title_full_unstemmed One-Step Generation of Reactive Superhydrophobic Surfaces via SiHCl(3)-Based Silicone Nanofilaments
title_short One-Step Generation of Reactive Superhydrophobic Surfaces via SiHCl(3)-Based Silicone Nanofilaments
title_sort one-step generation of reactive superhydrophobic surfaces via sihcl(3)-based silicone nanofilaments
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6328287/
https://www.ncbi.nlm.nih.gov/pubmed/30395470
http://dx.doi.org/10.1021/acs.langmuir.8b02247
work_keys_str_mv AT slagmansjoerd onestepgenerationofreactivesuperhydrophobicsurfacesviasihcl3basedsiliconenanofilaments
AT pujarisidharamp onestepgenerationofreactivesuperhydrophobicsurfacesviasihcl3basedsiliconenanofilaments
AT franssenmauricecr onestepgenerationofreactivesuperhydrophobicsurfacesviasihcl3basedsiliconenanofilaments
AT zuilhofhan onestepgenerationofreactivesuperhydrophobicsurfacesviasihcl3basedsiliconenanofilaments