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One-Step Generation of Reactive Superhydrophobic Surfaces via SiHCl(3)-Based Silicone Nanofilaments
[Image: see text] Superhydrophobic surfaces gain ever-growing attention because of their applicability in many (consumer) products/materials as they often display, among others, antifouling, anti-icing, and/or self-cleaning properties. A simple way to achieve superhydrophobicity is through the growt...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2018
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6328287/ https://www.ncbi.nlm.nih.gov/pubmed/30395470 http://dx.doi.org/10.1021/acs.langmuir.8b02247 |
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author | Slagman, Sjoerd Pujari, Sidharam P. Franssen, Maurice C. R. Zuilhof, Han |
author_facet | Slagman, Sjoerd Pujari, Sidharam P. Franssen, Maurice C. R. Zuilhof, Han |
author_sort | Slagman, Sjoerd |
collection | PubMed |
description | [Image: see text] Superhydrophobic surfaces gain ever-growing attention because of their applicability in many (consumer) products/materials as they often display, among others, antifouling, anti-icing, and/or self-cleaning properties. A simple way to achieve superhydrophobicity is through the growth of silicone nanofilaments. These nanofilaments, however, are very often nonreactive and thus difficult to utilize in subsequent chemistries. In response, we have developed a single-step procedure to grow (SiHCl(3)-based) silicone nanofilaments with selective reactivity that are intrinsically superhydrophobic. The silicone nanofilaments could be further functionalized via Pt-catalyzed hydrosilylation of exposed Si–H moieties. These surfaces are easily obtained using mild conditions and are stable under hydrolytic conditions (neutral water, 24 h at 80 °C) while remaining highly transparent, which makes them well suited for optical and photochemical experiments. |
format | Online Article Text |
id | pubmed-6328287 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | American
Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-63282872019-01-17 One-Step Generation of Reactive Superhydrophobic Surfaces via SiHCl(3)-Based Silicone Nanofilaments Slagman, Sjoerd Pujari, Sidharam P. Franssen, Maurice C. R. Zuilhof, Han Langmuir [Image: see text] Superhydrophobic surfaces gain ever-growing attention because of their applicability in many (consumer) products/materials as they often display, among others, antifouling, anti-icing, and/or self-cleaning properties. A simple way to achieve superhydrophobicity is through the growth of silicone nanofilaments. These nanofilaments, however, are very often nonreactive and thus difficult to utilize in subsequent chemistries. In response, we have developed a single-step procedure to grow (SiHCl(3)-based) silicone nanofilaments with selective reactivity that are intrinsically superhydrophobic. The silicone nanofilaments could be further functionalized via Pt-catalyzed hydrosilylation of exposed Si–H moieties. These surfaces are easily obtained using mild conditions and are stable under hydrolytic conditions (neutral water, 24 h at 80 °C) while remaining highly transparent, which makes them well suited for optical and photochemical experiments. American Chemical Society 2018-11-05 2018-11-13 /pmc/articles/PMC6328287/ /pubmed/30395470 http://dx.doi.org/10.1021/acs.langmuir.8b02247 Text en Copyright © 2018 American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes. |
spellingShingle | Slagman, Sjoerd Pujari, Sidharam P. Franssen, Maurice C. R. Zuilhof, Han One-Step Generation of Reactive Superhydrophobic Surfaces via SiHCl(3)-Based Silicone Nanofilaments |
title | One-Step Generation of Reactive Superhydrophobic Surfaces
via SiHCl(3)-Based Silicone Nanofilaments |
title_full | One-Step Generation of Reactive Superhydrophobic Surfaces
via SiHCl(3)-Based Silicone Nanofilaments |
title_fullStr | One-Step Generation of Reactive Superhydrophobic Surfaces
via SiHCl(3)-Based Silicone Nanofilaments |
title_full_unstemmed | One-Step Generation of Reactive Superhydrophobic Surfaces
via SiHCl(3)-Based Silicone Nanofilaments |
title_short | One-Step Generation of Reactive Superhydrophobic Surfaces
via SiHCl(3)-Based Silicone Nanofilaments |
title_sort | one-step generation of reactive superhydrophobic surfaces
via sihcl(3)-based silicone nanofilaments |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6328287/ https://www.ncbi.nlm.nih.gov/pubmed/30395470 http://dx.doi.org/10.1021/acs.langmuir.8b02247 |
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