Cargando…

Activation of Primary and Secondary Benzylic and Tertiary Alkyl (sp(3))C-F Bonds Inside a Self-Assembled Molecular Container

Alkyl fluorides are generally regarded as chemically inert. However, several literature examples describe the activation of alkyl (sp3)C-F bonds via strong Brønsted or Lewis acids under harsh conditions. We here report that catalytic amounts of the self-assembled resorcinarene capsule are able to ac...

Descripción completa

Detalles Bibliográficos
Autores principales: Köster, Jesper M., Häussinger, Daniel, Tiefenbacher, Konrad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6328483/
https://www.ncbi.nlm.nih.gov/pubmed/30662892
http://dx.doi.org/10.3389/fchem.2018.00639