Increasing the activity of copper exchanged mordenite in the direct isothermal conversion of methane to methanol by Pt and Pd doping

PtCu- and PdCu–mordenite allow for isothermal reaction at 200 °C for the stepwise methane to methanol conversion with comparably high yields. In contrast to traditional Cu-zeolites, these materials are more reactive under isothermal conditions than after high temperature activation.

Detalles Bibliográficos
Autores principales: Tomkins, P., Mansouri, A., L. Sushkevich, V., van der Wal, L. I., Bozbag, S. E., Krumeich, F., Ranocchiari, M., van Bokhoven, J. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6330690/
https://www.ncbi.nlm.nih.gov/pubmed/30713628
http://dx.doi.org/10.1039/c8sc02795a
Descripción
Sumario:PtCu- and PdCu–mordenite allow for isothermal reaction at 200 °C for the stepwise methane to methanol conversion with comparably high yields. In contrast to traditional Cu-zeolites, these materials are more reactive under isothermal conditions than after high temperature activation.

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