Synthesis of Chiral 1,4,2-Oxazaphosphepines

Synthesis and structural characterization of 1,4,2-oxazaphosphepines is described. The 1,4,2-oxazaphosphepines were obtained from reaction of chiral 1,3-benzoxazines with dichlorophenylphosphine or triethyl phosphite. The configuration of some of these compounds was stablished by X-ray analysis.

Detalles Bibliográficos
Autores principales: Salgado-Escobar, Oscar, Chavelas-Hernández, Leticia, Domínguez-Mendoza, Blanca E., Linzaga-Elizalde, Irma, Ordoñez, Mario
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6331794/
https://www.ncbi.nlm.nih.gov/pubmed/26230685
http://dx.doi.org/10.3390/molecules200813794
Descripción
Sumario:Synthesis and structural characterization of 1,4,2-oxazaphosphepines is described. The 1,4,2-oxazaphosphepines were obtained from reaction of chiral 1,3-benzoxazines with dichlorophenylphosphine or triethyl phosphite. The configuration of some of these compounds was stablished by X-ray analysis.

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