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Ambiphilic Frustrated Lewis Pair Exhibiting High Robustness and Reversible Water Activation: Towards the Metal-Free Hydrogenation of Carbon Dioxide

The synthesis and structural characterization of a phenylene-bridged Frustrated Lewis Pair (FLP) having a 2,2,6,6-tetramethylpiperidine (TMP) as the Lewis base and a 9-borabicyclo[3.3.1]nonane (BBN) as the Lewis acid is reported. This FLP exhibits unique robustness towards the products of carbon dio...

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Detalles Bibliográficos
Autores principales:	Rochette, Étienne, Courtemanche, Marc-André, Pulis, Alexander P., Bi, Wenhua, Fontaine, Frédéric-Georges
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2015
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6331835/ https://www.ncbi.nlm.nih.gov/pubmed/26132911 http://dx.doi.org/10.3390/molecules200711902

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