Cu and Boron Doped Carbon Nitride for Highly Selective Oxidation of Toluene to Benzaldehyde

A novel Cu and boron doped graphitic carbon nitride catalyst (Cu-CNB) was synthesized using cheap precursors and systematically characterized. The selective oxidation of toluene proceeded very smoothly over the catalyst at 70 °C using tert-butyl hydroperoxide (TBHP) as the oxidant to exclusively aff...

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Autores principales: Han, Hongling, Ding, Guodong, Wu, Tianbin, Yang, Dexin, Jiang, Tao, Han, Buxing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6331883/
https://www.ncbi.nlm.nih.gov/pubmed/26184147
http://dx.doi.org/10.3390/molecules200712686
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author Han, Hongling
Ding, Guodong
Wu, Tianbin
Yang, Dexin
Jiang, Tao
Han, Buxing
author_facet Han, Hongling
Ding, Guodong
Wu, Tianbin
Yang, Dexin
Jiang, Tao
Han, Buxing
author_sort Han, Hongling
collection PubMed
description A novel Cu and boron doped graphitic carbon nitride catalyst (Cu-CNB) was synthesized using cheap precursors and systematically characterized. The selective oxidation of toluene proceeded very smoothly over the catalyst at 70 °C using tert-butyl hydroperoxide (TBHP) as the oxidant to exclusively afford benzaldehyde. The catalyst can be used for at least five cycles without decrease in activity and selectivity.
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spelling pubmed-63318832019-01-24 Cu and Boron Doped Carbon Nitride for Highly Selective Oxidation of Toluene to Benzaldehyde Han, Hongling Ding, Guodong Wu, Tianbin Yang, Dexin Jiang, Tao Han, Buxing Molecules Article A novel Cu and boron doped graphitic carbon nitride catalyst (Cu-CNB) was synthesized using cheap precursors and systematically characterized. The selective oxidation of toluene proceeded very smoothly over the catalyst at 70 °C using tert-butyl hydroperoxide (TBHP) as the oxidant to exclusively afford benzaldehyde. The catalyst can be used for at least five cycles without decrease in activity and selectivity. MDPI 2015-07-13 /pmc/articles/PMC6331883/ /pubmed/26184147 http://dx.doi.org/10.3390/molecules200712686 Text en © 2015 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Han, Hongling
Ding, Guodong
Wu, Tianbin
Yang, Dexin
Jiang, Tao
Han, Buxing
Cu and Boron Doped Carbon Nitride for Highly Selective Oxidation of Toluene to Benzaldehyde
title Cu and Boron Doped Carbon Nitride for Highly Selective Oxidation of Toluene to Benzaldehyde
title_full Cu and Boron Doped Carbon Nitride for Highly Selective Oxidation of Toluene to Benzaldehyde
title_fullStr Cu and Boron Doped Carbon Nitride for Highly Selective Oxidation of Toluene to Benzaldehyde
title_full_unstemmed Cu and Boron Doped Carbon Nitride for Highly Selective Oxidation of Toluene to Benzaldehyde
title_short Cu and Boron Doped Carbon Nitride for Highly Selective Oxidation of Toluene to Benzaldehyde
title_sort cu and boron doped carbon nitride for highly selective oxidation of toluene to benzaldehyde
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6331883/
https://www.ncbi.nlm.nih.gov/pubmed/26184147
http://dx.doi.org/10.3390/molecules200712686
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AT wutianbin cuandborondopedcarbonnitrideforhighlyselectiveoxidationoftoluenetobenzaldehyde
AT yangdexin cuandborondopedcarbonnitrideforhighlyselectiveoxidationoftoluenetobenzaldehyde
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