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DFT Studies on the Stereoselectivity of α-Silyloxy Diazoalkane Cycloadditions

The intramolecular [3+2] cycloaddition (32CA) of alkene-tethered α-silyloxydiazoalkanes provides variable stereoselectivity in generating bicyclic pyrazolines where the silyloxy group is either syn or anti to the newly formed pyrazoline ring. To elucidate the origin of the stereoselectivity, density...

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Detalles Bibliográficos
Autores principales:	O’Connor, Matthew J., Liu, Huaqing, Lee, Daesung, Zhou, Tao, Xia, Yuanzhi
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2015
Materias:	Communication
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6331888/ https://www.ncbi.nlm.nih.gov/pubmed/26633338 http://dx.doi.org/10.3390/molecules201219783

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