Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans

Successive [2+4] cycloadditions of arynes and isobenzofurans by site-selective halogen-lithium exchange of 1,2-dihaloarenes were developed, allowing the rapid construction of polycyclic compounds which serve as a useful synthetic intermediates for the preparation of various polyacene derivatives.

Detalles Bibliográficos
Autores principales: Eda, Shohei, Hamura, Toshiyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6331892/
https://www.ncbi.nlm.nih.gov/pubmed/26512641
http://dx.doi.org/10.3390/molecules201019449
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author Eda, Shohei
Hamura, Toshiyuki
author_facet Eda, Shohei
Hamura, Toshiyuki
author_sort Eda, Shohei
collection PubMed
description Successive [2+4] cycloadditions of arynes and isobenzofurans by site-selective halogen-lithium exchange of 1,2-dihaloarenes were developed, allowing the rapid construction of polycyclic compounds which serve as a useful synthetic intermediates for the preparation of various polyacene derivatives.
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spelling pubmed-63318922019-01-24 Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans Eda, Shohei Hamura, Toshiyuki Molecules Communication Successive [2+4] cycloadditions of arynes and isobenzofurans by site-selective halogen-lithium exchange of 1,2-dihaloarenes were developed, allowing the rapid construction of polycyclic compounds which serve as a useful synthetic intermediates for the preparation of various polyacene derivatives. MDPI 2015-10-23 /pmc/articles/PMC6331892/ /pubmed/26512641 http://dx.doi.org/10.3390/molecules201019449 Text en © 2015 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Eda, Shohei
Hamura, Toshiyuki
Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans
title Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans
title_full Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans
title_fullStr Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans
title_full_unstemmed Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans
title_short Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans
title_sort selective halogen-lithium exchange of 1,2-dihaloarenes for successive [2+4] cycloadditions of arynes and isobenzofurans
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6331892/
https://www.ncbi.nlm.nih.gov/pubmed/26512641
http://dx.doi.org/10.3390/molecules201019449
work_keys_str_mv AT edashohei selectivehalogenlithiumexchangeof12dihaloarenesforsuccessive24cycloadditionsofarynesandisobenzofurans
AT hamuratoshiyuki selectivehalogenlithiumexchangeof12dihaloarenesforsuccessive24cycloadditionsofarynesandisobenzofurans

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