A Study on the Condensation Reaction of 4-Amino-3,5-dimethyl-1,2,4-triazole with Benzaldehydes: Structure and Spectroscopic Properties of Some New Stable Hemiaminals

Studies on the stable hemiaminals and Schiff bases formation in the reaction of substituted benzaldehydes with primary 3,5-dimethyl-1,2,4-triazole 4-amine were carried out under neutral conditions. These products were investigated by IR, Raman, MS, (1)H- and (13)C-NMR spectra as well as by X-ray cry...

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Autores principales: Wajda-Hermanowicz, Katarzyna, Pieniążczak, Damian, Zatajska, Aleksandra, Wróbel, Robert, Drabent, Krzysztof, Ciunik, Zbigniew
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332017/
https://www.ncbi.nlm.nih.gov/pubmed/26393552
http://dx.doi.org/10.3390/molecules200917109
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author Wajda-Hermanowicz, Katarzyna
Pieniążczak, Damian
Zatajska, Aleksandra
Wróbel, Robert
Drabent, Krzysztof
Ciunik, Zbigniew
author_facet Wajda-Hermanowicz, Katarzyna
Pieniążczak, Damian
Zatajska, Aleksandra
Wróbel, Robert
Drabent, Krzysztof
Ciunik, Zbigniew
author_sort Wajda-Hermanowicz, Katarzyna
collection PubMed
description Studies on the stable hemiaminals and Schiff bases formation in the reaction of substituted benzaldehydes with primary 3,5-dimethyl-1,2,4-triazole 4-amine were carried out under neutral conditions. These products were investigated by IR, Raman, MS, (1)H- and (13)C-NMR spectra as well as by X-ray crystallography. The effect of reaction conditions: temperature, polarity of the solvents utilized, substrate concentration and the ortho and para benzaldehyde substituents on the yield of products was also examined.
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spelling pubmed-63320172019-01-24 A Study on the Condensation Reaction of 4-Amino-3,5-dimethyl-1,2,4-triazole with Benzaldehydes: Structure and Spectroscopic Properties of Some New Stable Hemiaminals Wajda-Hermanowicz, Katarzyna Pieniążczak, Damian Zatajska, Aleksandra Wróbel, Robert Drabent, Krzysztof Ciunik, Zbigniew Molecules Article Studies on the stable hemiaminals and Schiff bases formation in the reaction of substituted benzaldehydes with primary 3,5-dimethyl-1,2,4-triazole 4-amine were carried out under neutral conditions. These products were investigated by IR, Raman, MS, (1)H- and (13)C-NMR spectra as well as by X-ray crystallography. The effect of reaction conditions: temperature, polarity of the solvents utilized, substrate concentration and the ortho and para benzaldehyde substituents on the yield of products was also examined. MDPI 2015-09-17 /pmc/articles/PMC6332017/ /pubmed/26393552 http://dx.doi.org/10.3390/molecules200917109 Text en © 2015 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Wajda-Hermanowicz, Katarzyna
Pieniążczak, Damian
Zatajska, Aleksandra
Wróbel, Robert
Drabent, Krzysztof
Ciunik, Zbigniew
A Study on the Condensation Reaction of 4-Amino-3,5-dimethyl-1,2,4-triazole with Benzaldehydes: Structure and Spectroscopic Properties of Some New Stable Hemiaminals
title A Study on the Condensation Reaction of 4-Amino-3,5-dimethyl-1,2,4-triazole with Benzaldehydes: Structure and Spectroscopic Properties of Some New Stable Hemiaminals
title_full A Study on the Condensation Reaction of 4-Amino-3,5-dimethyl-1,2,4-triazole with Benzaldehydes: Structure and Spectroscopic Properties of Some New Stable Hemiaminals
title_fullStr A Study on the Condensation Reaction of 4-Amino-3,5-dimethyl-1,2,4-triazole with Benzaldehydes: Structure and Spectroscopic Properties of Some New Stable Hemiaminals
title_full_unstemmed A Study on the Condensation Reaction of 4-Amino-3,5-dimethyl-1,2,4-triazole with Benzaldehydes: Structure and Spectroscopic Properties of Some New Stable Hemiaminals
title_short A Study on the Condensation Reaction of 4-Amino-3,5-dimethyl-1,2,4-triazole with Benzaldehydes: Structure and Spectroscopic Properties of Some New Stable Hemiaminals
title_sort study on the condensation reaction of 4-amino-3,5-dimethyl-1,2,4-triazole with benzaldehydes: structure and spectroscopic properties of some new stable hemiaminals
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332017/
https://www.ncbi.nlm.nih.gov/pubmed/26393552
http://dx.doi.org/10.3390/molecules200917109
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