Transfer Hydrogenation Employing Ethylene Diamine Bisborane in Water and Pd- and Ru-Nanoparticles in Ionic Liquids

Herein we demonstrate the use of ethylenediamine bisborane (EDAB) as a suitable hydrogen source for transfer hydrogenation reactions on C-C double bonds mediated by metal nanoparticles. Moreover, EDAB also acts as a reducing agent for carbonyl functionalities in water under metal-free conditions.

Detalles Bibliográficos
Autores principales: Sahler, Sebastian, Scott, Martin, Gedig, Christian, Prechtl, Martin H. G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332364/
https://www.ncbi.nlm.nih.gov/pubmed/26393549
http://dx.doi.org/10.3390/molecules200917058
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author Sahler, Sebastian
Scott, Martin
Gedig, Christian
Prechtl, Martin H. G.
author_facet Sahler, Sebastian
Scott, Martin
Gedig, Christian
Prechtl, Martin H. G.
author_sort Sahler, Sebastian
collection PubMed
description Herein we demonstrate the use of ethylenediamine bisborane (EDAB) as a suitable hydrogen source for transfer hydrogenation reactions on C-C double bonds mediated by metal nanoparticles. Moreover, EDAB also acts as a reducing agent for carbonyl functionalities in water under metal-free conditions.
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spelling pubmed-63323642019-01-24 Transfer Hydrogenation Employing Ethylene Diamine Bisborane in Water and Pd- and Ru-Nanoparticles in Ionic Liquids Sahler, Sebastian Scott, Martin Gedig, Christian Prechtl, Martin H. G. Molecules Communication Herein we demonstrate the use of ethylenediamine bisborane (EDAB) as a suitable hydrogen source for transfer hydrogenation reactions on C-C double bonds mediated by metal nanoparticles. Moreover, EDAB also acts as a reducing agent for carbonyl functionalities in water under metal-free conditions. MDPI 2015-09-17 /pmc/articles/PMC6332364/ /pubmed/26393549 http://dx.doi.org/10.3390/molecules200917058 Text en © 2015 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Sahler, Sebastian
Scott, Martin
Gedig, Christian
Prechtl, Martin H. G.
Transfer Hydrogenation Employing Ethylene Diamine Bisborane in Water and Pd- and Ru-Nanoparticles in Ionic Liquids
title Transfer Hydrogenation Employing Ethylene Diamine Bisborane in Water and Pd- and Ru-Nanoparticles in Ionic Liquids
title_full Transfer Hydrogenation Employing Ethylene Diamine Bisborane in Water and Pd- and Ru-Nanoparticles in Ionic Liquids
title_fullStr Transfer Hydrogenation Employing Ethylene Diamine Bisborane in Water and Pd- and Ru-Nanoparticles in Ionic Liquids
title_full_unstemmed Transfer Hydrogenation Employing Ethylene Diamine Bisborane in Water and Pd- and Ru-Nanoparticles in Ionic Liquids
title_short Transfer Hydrogenation Employing Ethylene Diamine Bisborane in Water and Pd- and Ru-Nanoparticles in Ionic Liquids
title_sort transfer hydrogenation employing ethylene diamine bisborane in water and pd- and ru-nanoparticles in ionic liquids
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332364/
https://www.ncbi.nlm.nih.gov/pubmed/26393549
http://dx.doi.org/10.3390/molecules200917058
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