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Exploring the Reactivity of Na[W(2)(μ-Cl)(3)Cl(4)(THF)(2)]∙(THF)(3) towards the Polymerization of Selected Cycloolefins

The bimetallic compound Na[W(2)(μ-Cl)(3)Cl(4)(THF)(2)]·(THF)(3) (1, {W( 3 )W}(6+), a′(2)e′(4)) is a highly efficient room-temperature initiator for ring opening metathesis polymerization (ROMP) of norbornene (NBE) and some of its derivatives. In most cases, addition of phenylacetylene (PA) as co-ini...

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Detalles Bibliográficos
Autores principales: Saragas, Nikolaos, Floros, Georgios, Raptopoulos, Grigorios, Pitsikalis, Marinos, Paraskevopoulou, Patrina, Mertis, Konstantinos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332418/
https://www.ncbi.nlm.nih.gov/pubmed/26670223
http://dx.doi.org/10.3390/molecules201219810