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Exploring the Reactivity of Na[W(2)(μ-Cl)(3)Cl(4)(THF)(2)]∙(THF)(3) towards the Polymerization of Selected Cycloolefins
The bimetallic compound Na[W(2)(μ-Cl)(3)Cl(4)(THF)(2)]·(THF)(3) (1, {W( 3 )W}(6+), a′(2)e′(4)) is a highly efficient room-temperature initiator for ring opening metathesis polymerization (ROMP) of norbornene (NBE) and some of its derivatives. In most cases, addition of phenylacetylene (PA) as co-ini...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332418/ https://www.ncbi.nlm.nih.gov/pubmed/26670223 http://dx.doi.org/10.3390/molecules201219810 |