Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes

The oxidation of iodoarenes is central to the field of hypervalent iodine chemistry. It was found that the metathetical redox reaction between (diacetoxyiodo)arenes and iodoarenes is possible in the presence of a catalytic amount of Lewis acid. This discovery opens a new strategy to access (diacetox...

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Detalles Bibliográficos
Autores principales: Jobin-Des Lauriers, Antoine, Legault, Claude Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332457/
https://www.ncbi.nlm.nih.gov/pubmed/26694343
http://dx.doi.org/10.3390/molecules201219874
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author Jobin-Des Lauriers, Antoine
Legault, Claude Y.
author_facet Jobin-Des Lauriers, Antoine
Legault, Claude Y.
author_sort Jobin-Des Lauriers, Antoine
collection PubMed
description The oxidation of iodoarenes is central to the field of hypervalent iodine chemistry. It was found that the metathetical redox reaction between (diacetoxyiodo)arenes and iodoarenes is possible in the presence of a catalytic amount of Lewis acid. This discovery opens a new strategy to access (diacetoxyiodo)arenes. A computational study is provided to rationalize the results observed.
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spelling pubmed-63324572019-01-24 Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes Jobin-Des Lauriers, Antoine Legault, Claude Y. Molecules Article The oxidation of iodoarenes is central to the field of hypervalent iodine chemistry. It was found that the metathetical redox reaction between (diacetoxyiodo)arenes and iodoarenes is possible in the presence of a catalytic amount of Lewis acid. This discovery opens a new strategy to access (diacetoxyiodo)arenes. A computational study is provided to rationalize the results observed. MDPI 2015-12-17 /pmc/articles/PMC6332457/ /pubmed/26694343 http://dx.doi.org/10.3390/molecules201219874 Text en © 2015 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons by Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Jobin-Des Lauriers, Antoine
Legault, Claude Y.
Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes
title Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes
title_full Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes
title_fullStr Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes
title_full_unstemmed Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes
title_short Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes
title_sort metathetical redox reaction of (diacetoxyiodo)arenes and iodoarenes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6332457/
https://www.ncbi.nlm.nih.gov/pubmed/26694343
http://dx.doi.org/10.3390/molecules201219874
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