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Direct observation of the intermediate in an ultrafast isomerization

Using a combination of two-dimensional infrared (2D IR) and variable temperature Fourier transform infrared (FTIR) spectroscopies the rapid structural isomerization of a five-coordinate ruthenium complex is investigated. In methylene chloride, three exchanging isomers were observed: (1) square pyram...

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Detalles Bibliográficos
Autores principales:	Porter, Tyler M., Wang, Jiaxi, Li, Yingmin, Xiang, Bo, Salsman, Catherine, Miller, Joel S., Xiong, Wei, Kubiak, Clifford P.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6333165/ https://www.ncbi.nlm.nih.gov/pubmed/30713623 http://dx.doi.org/10.1039/c8sc03258k

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