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Chiral hybrid materials based on pyrrolidine building units to perform asymmetric Michael additions with high stereocontrol

A new chiral mesoporous hybrid material was synthesized based on pyrrolidine units included in a siliceous framework, HybPyr, and integrated into the organic–inorganic structure, from a specific bis-silylated precursor. A fluoride sol–gel methodology under soft synthesis conditions and in the absenc...

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Detalles Bibliográficos
Autores principales: Llopis, Sebastián, García, Teresa, Cantín, Ángel, Velty, Alexandra, Díaz, Urbano, Corma, Avelino
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6333262/
https://www.ncbi.nlm.nih.gov/pubmed/30713656
http://dx.doi.org/10.1039/c8cy01650j