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Chiral hybrid materials based on pyrrolidine building units to perform asymmetric Michael additions with high stereocontrol
A new chiral mesoporous hybrid material was synthesized based on pyrrolidine units included in a siliceous framework, HybPyr, and integrated into the organic–inorganic structure, from a specific bis-silylated precursor. A fluoride sol–gel methodology under soft synthesis conditions and in the absenc...
Autores principales: | Llopis, Sebastián, García, Teresa, Cantín, Ángel, Velty, Alexandra, Díaz, Urbano, Corma, Avelino |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6333262/ https://www.ncbi.nlm.nih.gov/pubmed/30713656 http://dx.doi.org/10.1039/c8cy01650j |
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