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Understanding the desulphurization process in an ionic porous aromatic framework

An ionic porous aromatic framework, iPAF-1, was successfully synthesized from a designed monomer with imidazolium functional groups. The iPAF-1 exhibits the highest dibenzothiophene uptake among all reported adsorptive desulphurization adsorbents. The so-called precursor designed synthetic route pro...

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Detalles Bibliográficos
Autores principales: Tian, Yuyang, Song, Jian, Zhu, Youliang, Zhao, Huanyu, Muhammad, Faheem, Ma, Tingting, Chen, Mo, Zhu, Guangshan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6334719/
https://www.ncbi.nlm.nih.gov/pubmed/30746102
http://dx.doi.org/10.1039/c8sc03727b
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author Tian, Yuyang
Song, Jian
Zhu, Youliang
Zhao, Huanyu
Muhammad, Faheem
Ma, Tingting
Chen, Mo
Zhu, Guangshan
author_facet Tian, Yuyang
Song, Jian
Zhu, Youliang
Zhao, Huanyu
Muhammad, Faheem
Ma, Tingting
Chen, Mo
Zhu, Guangshan
author_sort Tian, Yuyang
collection PubMed
description An ionic porous aromatic framework, iPAF-1, was successfully synthesized from a designed monomer with imidazolium functional groups. The iPAF-1 exhibits the highest dibenzothiophene uptake among all reported adsorptive desulphurization adsorbents. The so-called precursor designed synthetic route provides the stoichiometric and homogeneous introduction of desired functional groups into the framework. Molecular dynamics simulation was performed to understand the structure and the desulphurization process within the amorphous iPAF-1. The insight into the key role of the moderate bonding interaction between the adsorbate and the functional groups of iPAF-1 for improved uptake is highlighted in this work.
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spelling pubmed-63347192019-02-11 Understanding the desulphurization process in an ionic porous aromatic framework Tian, Yuyang Song, Jian Zhu, Youliang Zhao, Huanyu Muhammad, Faheem Ma, Tingting Chen, Mo Zhu, Guangshan Chem Sci Chemistry An ionic porous aromatic framework, iPAF-1, was successfully synthesized from a designed monomer with imidazolium functional groups. The iPAF-1 exhibits the highest dibenzothiophene uptake among all reported adsorptive desulphurization adsorbents. The so-called precursor designed synthetic route provides the stoichiometric and homogeneous introduction of desired functional groups into the framework. Molecular dynamics simulation was performed to understand the structure and the desulphurization process within the amorphous iPAF-1. The insight into the key role of the moderate bonding interaction between the adsorbate and the functional groups of iPAF-1 for improved uptake is highlighted in this work. Royal Society of Chemistry 2018-10-23 /pmc/articles/PMC6334719/ /pubmed/30746102 http://dx.doi.org/10.1039/c8sc03727b Text en This journal is © The Royal Society of Chemistry 2019 https://creativecommons.org/licenses/by-nc/3.0/This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)
spellingShingle Chemistry
Tian, Yuyang
Song, Jian
Zhu, Youliang
Zhao, Huanyu
Muhammad, Faheem
Ma, Tingting
Chen, Mo
Zhu, Guangshan
Understanding the desulphurization process in an ionic porous aromatic framework
title Understanding the desulphurization process in an ionic porous aromatic framework
title_full Understanding the desulphurization process in an ionic porous aromatic framework
title_fullStr Understanding the desulphurization process in an ionic porous aromatic framework
title_full_unstemmed Understanding the desulphurization process in an ionic porous aromatic framework
title_short Understanding the desulphurization process in an ionic porous aromatic framework
title_sort understanding the desulphurization process in an ionic porous aromatic framework
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6334719/
https://www.ncbi.nlm.nih.gov/pubmed/30746102
http://dx.doi.org/10.1039/c8sc03727b
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