Gold-catalyzed ethylene cyclopropanation

Ethylene can be directly converted into ethyl 1-cyclopropylcarboxylate upon reaction with ethyl diazoacetate (N(2)CHCO(2)Et, EDA) in the presence of catalytic amounts of IPrAuCl/NaBAr(F)(4) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene; BAr(F)(4) = tetrakis(3,5-bis(trifluoromethyl)phenyl)...

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Detalles Bibliográficos
Autores principales: Rull, Silvia G, Olmos, Andrea, Pérez, Pedro J
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6334794/
https://www.ncbi.nlm.nih.gov/pubmed/30680040
http://dx.doi.org/10.3762/bjoc.15.7
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author Rull, Silvia G
Olmos, Andrea
Pérez, Pedro J
author_facet Rull, Silvia G
Olmos, Andrea
Pérez, Pedro J
author_sort Rull, Silvia G
collection PubMed
description Ethylene can be directly converted into ethyl 1-cyclopropylcarboxylate upon reaction with ethyl diazoacetate (N(2)CHCO(2)Et, EDA) in the presence of catalytic amounts of IPrAuCl/NaBAr(F)(4) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene; BAr(F)(4) = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate).
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spelling pubmed-63347942019-01-24 Gold-catalyzed ethylene cyclopropanation Rull, Silvia G Olmos, Andrea Pérez, Pedro J Beilstein J Org Chem Full Research Paper Ethylene can be directly converted into ethyl 1-cyclopropylcarboxylate upon reaction with ethyl diazoacetate (N(2)CHCO(2)Et, EDA) in the presence of catalytic amounts of IPrAuCl/NaBAr(F)(4) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene; BAr(F)(4) = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate). Beilstein-Institut 2019-01-07 /pmc/articles/PMC6334794/ /pubmed/30680040 http://dx.doi.org/10.3762/bjoc.15.7 Text en Copyright © 2019, Rull et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Rull, Silvia G
Olmos, Andrea
Pérez, Pedro J
Gold-catalyzed ethylene cyclopropanation
title Gold-catalyzed ethylene cyclopropanation
title_full Gold-catalyzed ethylene cyclopropanation
title_fullStr Gold-catalyzed ethylene cyclopropanation
title_full_unstemmed Gold-catalyzed ethylene cyclopropanation
title_short Gold-catalyzed ethylene cyclopropanation
title_sort gold-catalyzed ethylene cyclopropanation
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6334794/
https://www.ncbi.nlm.nih.gov/pubmed/30680040
http://dx.doi.org/10.3762/bjoc.15.7
work_keys_str_mv AT rullsilviag goldcatalyzedethylenecyclopropanation
AT olmosandrea goldcatalyzedethylenecyclopropanation
AT perezpedroj goldcatalyzedethylenecyclopropanation

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