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The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique
Polymeric thin films patterned with honeycomb structures were prepared from poly(x-chlorostyrene) and statistical poly(x-chlorostyrene-co-styrene) copolymers by static breath figure method. Each polymeric sample was synthesized by free radical polymerization and its solution in tetrahydrofuran cast...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6337389/ https://www.ncbi.nlm.nih.gov/pubmed/30621027 http://dx.doi.org/10.3390/ma12010167 |
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author | Ruiz-Rubio, Leire Pérez-Álvarez, Leyre Sanchez-Bodón, Julia Arrighi, Valeria Vilas-Vilela, José Luis |
author_facet | Ruiz-Rubio, Leire Pérez-Álvarez, Leyre Sanchez-Bodón, Julia Arrighi, Valeria Vilas-Vilela, José Luis |
author_sort | Ruiz-Rubio, Leire |
collection | PubMed |
description | Polymeric thin films patterned with honeycomb structures were prepared from poly(x-chlorostyrene) and statistical poly(x-chlorostyrene-co-styrene) copolymers by static breath figure method. Each polymeric sample was synthesized by free radical polymerization and its solution in tetrahydrofuran cast on glass wafers under 90% relative humidity (RH). The effect of the chorine substitution in the topography and conformational entropy was evaluated. The entropy of each sample was calculated by using Voronoi tessellation. The obtained results revealed that these materials could be a suitable toolbox to develop a honeycomb patterns with a wide range of pore sizes for a potential use in contact guidance induced culture. |
format | Online Article Text |
id | pubmed-6337389 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-63373892019-01-22 The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique Ruiz-Rubio, Leire Pérez-Álvarez, Leyre Sanchez-Bodón, Julia Arrighi, Valeria Vilas-Vilela, José Luis Materials (Basel) Article Polymeric thin films patterned with honeycomb structures were prepared from poly(x-chlorostyrene) and statistical poly(x-chlorostyrene-co-styrene) copolymers by static breath figure method. Each polymeric sample was synthesized by free radical polymerization and its solution in tetrahydrofuran cast on glass wafers under 90% relative humidity (RH). The effect of the chorine substitution in the topography and conformational entropy was evaluated. The entropy of each sample was calculated by using Voronoi tessellation. The obtained results revealed that these materials could be a suitable toolbox to develop a honeycomb patterns with a wide range of pore sizes for a potential use in contact guidance induced culture. MDPI 2019-01-07 /pmc/articles/PMC6337389/ /pubmed/30621027 http://dx.doi.org/10.3390/ma12010167 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Ruiz-Rubio, Leire Pérez-Álvarez, Leyre Sanchez-Bodón, Julia Arrighi, Valeria Vilas-Vilela, José Luis The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique |
title | The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique |
title_full | The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique |
title_fullStr | The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique |
title_full_unstemmed | The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique |
title_short | The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique |
title_sort | effect of the isomeric chlorine substitutions on the honeycomb-patterned films of poly(x-chlorostyrene)s/polystyrene blends and copolymers via static breath figure technique |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6337389/ https://www.ncbi.nlm.nih.gov/pubmed/30621027 http://dx.doi.org/10.3390/ma12010167 |
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