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The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique

Polymeric thin films patterned with honeycomb structures were prepared from poly(x-chlorostyrene) and statistical poly(x-chlorostyrene-co-styrene) copolymers by static breath figure method. Each polymeric sample was synthesized by free radical polymerization and its solution in tetrahydrofuran cast...

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Autores principales: Ruiz-Rubio, Leire, Pérez-Álvarez, Leyre, Sanchez-Bodón, Julia, Arrighi, Valeria, Vilas-Vilela, José Luis
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6337389/
https://www.ncbi.nlm.nih.gov/pubmed/30621027
http://dx.doi.org/10.3390/ma12010167
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author Ruiz-Rubio, Leire
Pérez-Álvarez, Leyre
Sanchez-Bodón, Julia
Arrighi, Valeria
Vilas-Vilela, José Luis
author_facet Ruiz-Rubio, Leire
Pérez-Álvarez, Leyre
Sanchez-Bodón, Julia
Arrighi, Valeria
Vilas-Vilela, José Luis
author_sort Ruiz-Rubio, Leire
collection PubMed
description Polymeric thin films patterned with honeycomb structures were prepared from poly(x-chlorostyrene) and statistical poly(x-chlorostyrene-co-styrene) copolymers by static breath figure method. Each polymeric sample was synthesized by free radical polymerization and its solution in tetrahydrofuran cast on glass wafers under 90% relative humidity (RH). The effect of the chorine substitution in the topography and conformational entropy was evaluated. The entropy of each sample was calculated by using Voronoi tessellation. The obtained results revealed that these materials could be a suitable toolbox to develop a honeycomb patterns with a wide range of pore sizes for a potential use in contact guidance induced culture.
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spelling pubmed-63373892019-01-22 The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique Ruiz-Rubio, Leire Pérez-Álvarez, Leyre Sanchez-Bodón, Julia Arrighi, Valeria Vilas-Vilela, José Luis Materials (Basel) Article Polymeric thin films patterned with honeycomb structures were prepared from poly(x-chlorostyrene) and statistical poly(x-chlorostyrene-co-styrene) copolymers by static breath figure method. Each polymeric sample was synthesized by free radical polymerization and its solution in tetrahydrofuran cast on glass wafers under 90% relative humidity (RH). The effect of the chorine substitution in the topography and conformational entropy was evaluated. The entropy of each sample was calculated by using Voronoi tessellation. The obtained results revealed that these materials could be a suitable toolbox to develop a honeycomb patterns with a wide range of pore sizes for a potential use in contact guidance induced culture. MDPI 2019-01-07 /pmc/articles/PMC6337389/ /pubmed/30621027 http://dx.doi.org/10.3390/ma12010167 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Ruiz-Rubio, Leire
Pérez-Álvarez, Leyre
Sanchez-Bodón, Julia
Arrighi, Valeria
Vilas-Vilela, José Luis
The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique
title The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique
title_full The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique
title_fullStr The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique
title_full_unstemmed The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique
title_short The Effect of the Isomeric Chlorine Substitutions on the Honeycomb-Patterned Films of Poly(x-chlorostyrene)s/Polystyrene Blends and Copolymers via Static Breath Figure Technique
title_sort effect of the isomeric chlorine substitutions on the honeycomb-patterned films of poly(x-chlorostyrene)s/polystyrene blends and copolymers via static breath figure technique
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6337389/
https://www.ncbi.nlm.nih.gov/pubmed/30621027
http://dx.doi.org/10.3390/ma12010167
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