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Highly Efficient Liquid-Phase Hydrogenation of Naringin Using a Recyclable Pd/C Catalyst

A highly efficient liquid-phase hydrogenation reaction using a recyclable palladium on carbon (Pd/C) catalyst has been used for the transformation of naringin to its corresponding dihydrochalcone. The effects of various solvents on the hydrogenation process were studied, with water being identified...

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Detalles Bibliográficos
Autores principales: Zhao, Jiamin, Yuan, Ying, Meng, Xiuhong, Duan, Linhai, Zhou, Rujin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6337632/
https://www.ncbi.nlm.nih.gov/pubmed/30586873
http://dx.doi.org/10.3390/ma12010046
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author Zhao, Jiamin
Yuan, Ying
Meng, Xiuhong
Duan, Linhai
Zhou, Rujin
author_facet Zhao, Jiamin
Yuan, Ying
Meng, Xiuhong
Duan, Linhai
Zhou, Rujin
author_sort Zhao, Jiamin
collection PubMed
description A highly efficient liquid-phase hydrogenation reaction using a recyclable palladium on carbon (Pd/C) catalyst has been used for the transformation of naringin to its corresponding dihydrochalcone. The effects of various solvents on the hydrogenation process were studied, with water being identified as the optimal solvent. The analysis also revealed that sodium hydroxide (NaOH) can accumulate on the surface of the Pd/C catalyst in alcoholic solvents, leading to its inactivation. The higher solubility of NaOH in water implies that it remains in solution and does not accumulate on the Pd/C catalyst surface, ensuring the catalytic activity and stability.
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spelling pubmed-63376322019-01-22 Highly Efficient Liquid-Phase Hydrogenation of Naringin Using a Recyclable Pd/C Catalyst Zhao, Jiamin Yuan, Ying Meng, Xiuhong Duan, Linhai Zhou, Rujin Materials (Basel) Article A highly efficient liquid-phase hydrogenation reaction using a recyclable palladium on carbon (Pd/C) catalyst has been used for the transformation of naringin to its corresponding dihydrochalcone. The effects of various solvents on the hydrogenation process were studied, with water being identified as the optimal solvent. The analysis also revealed that sodium hydroxide (NaOH) can accumulate on the surface of the Pd/C catalyst in alcoholic solvents, leading to its inactivation. The higher solubility of NaOH in water implies that it remains in solution and does not accumulate on the Pd/C catalyst surface, ensuring the catalytic activity and stability. MDPI 2018-12-24 /pmc/articles/PMC6337632/ /pubmed/30586873 http://dx.doi.org/10.3390/ma12010046 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zhao, Jiamin
Yuan, Ying
Meng, Xiuhong
Duan, Linhai
Zhou, Rujin
Highly Efficient Liquid-Phase Hydrogenation of Naringin Using a Recyclable Pd/C Catalyst
title Highly Efficient Liquid-Phase Hydrogenation of Naringin Using a Recyclable Pd/C Catalyst
title_full Highly Efficient Liquid-Phase Hydrogenation of Naringin Using a Recyclable Pd/C Catalyst
title_fullStr Highly Efficient Liquid-Phase Hydrogenation of Naringin Using a Recyclable Pd/C Catalyst
title_full_unstemmed Highly Efficient Liquid-Phase Hydrogenation of Naringin Using a Recyclable Pd/C Catalyst
title_short Highly Efficient Liquid-Phase Hydrogenation of Naringin Using a Recyclable Pd/C Catalyst
title_sort highly efficient liquid-phase hydrogenation of naringin using a recyclable pd/c catalyst
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6337632/
https://www.ncbi.nlm.nih.gov/pubmed/30586873
http://dx.doi.org/10.3390/ma12010046
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