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Photoredox-mediated remote C(sp(3))–H heteroarylation of free alcohols

We report an efficient and economical method for remote δ C(sp(3))–H heteroarylation of free aliphatic alcohols using a hypervalent iodine PFBI-OH oxidant under photoredox catalysis. The reaction sequence involves in situ alcoholysis of PFBI-OH with alcohol, generation of an alkoxy radical intermedi...

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Detalles Bibliográficos
Autores principales:	Li, Guo-Xing, Hu, Xiafei, He, Gang, Chen, Gong
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6345347/ https://www.ncbi.nlm.nih.gov/pubmed/30774869 http://dx.doi.org/10.1039/c8sc04134b

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