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Conformer-specific [1,2]H-tunnelling in captodatively-stabilized cyanohydroxycarbene (NC–C[combining umlaut]–OH)

We report the gas-phase preparation of cyanohydroxycarbene by high-vacuum flash pyrolysis of ethyl 2-cyano-2-oxoacetate and subsequent trapping of the pyrolysate in an inert argon matrix at 3 K. After irradiation of the matrix with green light for a few seconds singlet trans-cyanohydroxycarbene rear...

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Detalles Bibliográficos
Autores principales: Eckhardt, André K., Erb, Frederik R., Schreiner, Peter R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6345350/
https://www.ncbi.nlm.nih.gov/pubmed/30774874
http://dx.doi.org/10.1039/c8sc03720e

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