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Reduction of CO(2) by a masked two-coordinate cobalt(i) complex and characterization of a proposed oxodicobalt(ii) intermediate

Fixation and chemical reduction of CO(2) are important for utilization of this abundant resource, and understanding the detailed mechanism of C–O cleavage is needed for rational development of CO(2) reduction methods. Here, we describe a detailed analysis of the mechanism of the reaction of a masked...

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Detalles Bibliográficos
Autores principales: Roy, Lisa, Al-Afyouni, Malik H., DeRosha, Daniel E., Mondal, Bhaskar, DiMucci, Ida M., Lancaster, Kyle M., Shearer, Jason, Bill, Eckhard, Brennessel, William W., Neese, Frank, Ye, Shengfa, Holland, Patrick L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6346294/
https://www.ncbi.nlm.nih.gov/pubmed/30774886
http://dx.doi.org/10.1039/c8sc02599a