Cargando…

Reduction of CO(2) by a masked two-coordinate cobalt(i) complex and characterization of a proposed oxodicobalt(ii) intermediate

Fixation and chemical reduction of CO(2) are important for utilization of this abundant resource, and understanding the detailed mechanism of C–O cleavage is needed for rational development of CO(2) reduction methods. Here, we describe a detailed analysis of the mechanism of the reaction of a masked...

Descripción completa

Detalles Bibliográficos
Autores principales:	Roy, Lisa, Al-Afyouni, Malik H., DeRosha, Daniel E., Mondal, Bhaskar, DiMucci, Ida M., Lancaster, Kyle M., Shearer, Jason, Bill, Eckhard, Brennessel, William W., Neese, Frank, Ye, Shengfa, Holland, Patrick L.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6346294/ https://www.ncbi.nlm.nih.gov/pubmed/30774886 http://dx.doi.org/10.1039/c8sc02599a

Ejemplares similares

Planar three-coordinate iron sulfide in a synthetic [4Fe-3S] cluster with biomimetic reactivity
por: DeRosha, Daniel E., et al.
Publicado: (2019)

Electron Paramagnetic Resonance Signature of Tetragonal Low Spin Iron(V)-Nitrido and -Oxo Complexes Derived from the Electronic Structure Analysis of Heme and Non-Heme Archetypes
por: Chang, Hao-Ching, et al.
Publicado: (2019)

Isolation and Characterization of a Tetramethyliron(III) Ferrate: An Intermediate in the Reduction Pathway of Ferric Salts with MeMgBr
por: Al-Afyouni, Malik H., et al.
Publicado: (2014)

Scrutinizing metal–ligand covalency and redox non-innocence via nitrogen K-edge X-ray absorption spectroscopy
por: Lukens, James T., et al.
Publicado: (2019)

Cobalt-Catalyzed Hydrosilylation of Carbon Dioxide to the Formic Acid, Formaldehyde, and Methanol Level—How to Control the Catalytic Network?
por: Cramer, Hanna H., et al.
Publicado: (2021)

Bis(η(5)-pentamethylcyclopentadienyl)cobalt(II)
por: Clark, Meghan M., et al.
Publicado: (2009)

Air-stable four-coordinate cobalt(ii) single-ion magnets: experimental and ab initio ligand field analyses of correlations between dihedral angles and magnetic anisotropy
por: Gupta, Sandeep K., et al.
Publicado: (2023)

Magnetic circular dichroism and computational study of mononuclear and dinuclear iron(iv) complexes
por: Ye, Shengfa, et al.
Publicado: (2015)

Probing the electronic and mechanistic roles of the μ(4)-sulfur atom in a synthetic Cu(Z) model system
por: Rathnayaka, Suresh C., et al.
Publicado: (2020)

Conversion of a Fleeting Open‐Shell Iron Nitride into an Iron Nitrosyl
por: Chang, Hao‐Ching, et al.
Publicado: (2019)

Machine Learning Reveals Missing Edges and Putative Interaction Mechanisms in Microbial Ecosystem Networks
por: DiMucci, Demetrius, et al.
Publicado: (2018)

BowSaw: Inferring Higher-Order Trait Interactions Associated With Complex Biological Phenotypes
por: DiMucci, Demetrius, et al.
Publicado: (2021)

True and masked three-coordinate T-shaped platinum(II) intermediates
por: Ortuño, Manuel A, et al.
Publicado: (2013)

(2.2.2-Cryptand)potassium tetracarbonylcobaltate(−I)
por: Brennessel, William W., et al.
Publicado: (2014)

Heteroleptic samarium(iii) halide complexes probed by fluorescence-detected L(3)-edge X-ray absorption spectroscopy
por: Goodwin, Conrad A. P., et al.
Publicado: (2018)

Synthesis, Spectroscopy, and Hydrogen/Deuterium Exchange in High-Spin Iron(II) Hydride Complexes
por: Dugan, Thomas R., et al.
Publicado: (2014)

Electronic structure analysis of electrochemical CO(2) reduction by iron-porphyrins reveals basic requirements for design of catalysts bearing non-innocent ligands
por: Tarrago, Maxime, et al.
Publicado: (2022)

(2.2.2-Cryptand)potassium tetrakis(η(2)-ethylene)cobaltate(−I)
por: Brennessel, William W., et al.
Publicado: (2012)

Coordinatively Unsaturated Metallates of Cobalt(II), Nickel(II), and Zinc(II) Guarded by a Rigid and Narrow Void
por: Hastings, Christopher D., et al.
Publicado: (2023)

Nitrene transfer from a sterically confined copper nitrenoid dipyrrin complex
por: Carsch, Kurtis M., et al.
Publicado: (2023)

Spectroscopic Evidence for a Cobalt-Bound Peroxyhemiacetal Intermediate
por: Son, Yeongjin, et al.
Publicado: (2021)

Crystal structure of [(1,2,3,4,11,12-η)-anthracene]tris(trimethylstannyl)cobalt(III)
por: Brennessel, William W., et al.
Publicado: (2014)

Heteroleptic Samarium(III) Chalcogenide Complexes: Opportunities for Giant Exchange Coupling in Bridging σ- and π-Radical Lanthanide Dichalcogenides
por: Goodwin, Conrad A. P., et al.
Publicado: (2020)

A Multidisciplinary Quality Improvement Program to Improve Diabetes Care at a Free Clinic
por: Hopper, Wade, et al.
Publicado: (2023)

A Two-Coordinate Iron(II) Imido Complex with NHC Ligation: Synthesis, Characterization, and Its Diversified Reactivity of Nitrene Transfer and C–H Bond Activation
por: Cheng, Jun, et al.
Publicado: (2019)

([2.2.2]Cryptand-κ(6) O)potassium (η(4)-cyclooctadiene)bis(η(2)-pyrene)cobaltate(1−) pentane hemisolvate
por: Brennessel, William W., et al.
Publicado: (2012)

A four-coordinate cobalt(II) single-ion magnet with coercivity and a very high energy barrier
por: Rechkemmer, Yvonne, et al.
Publicado: (2016)

Synthesis, Characterization, and Nitrogenase-Relevant Reactions of an Iron Sulfide Complex with a Bridging Hydride
por: Arnet, Nicholas A., et al.
Publicado: (2015)

Chemistry and Quantum Mechanics in 2019: Give Us Insight and Numbers
por: Neese, Frank, et al.
Publicado: (2019)

Isolation of a Homoleptic Non-oxo Mo(V) Alkoxide Complex: Synthesis, Structure, and Electronic Properties of Penta-tert-Butoxymolybdenum
por: Hillenbrand, Julius, et al.
Publicado: (2020)

A five-coordinate Mn(iv) intermediate in biological water oxidation: spectroscopic signature and a pivot mechanism for water binding
por: Retegan, Marius, et al.
Publicado: (2016)

Scrutinizing formally Ni(IV) centers through the lenses of core spectroscopy, molecular orbital theory, and valence bond theory
por: DiMucci, Ida M., et al.
Publicado: (2023)

Crystal structure of (18-crown-6)potassium(I) [(1,2,3,4,5-η)-cycloheptadienyl][(1,2,3-η)-cycloheptatrienyl]cobalt(I)
por: Brennessel, William W., et al.
Publicado: (2015)

Enhanced Fe-Centered Redox Flexibility in Fe–Ti Heterobimetallic Complexes
por: Moore, James T., et al.
Publicado: (2019)

Catalytic Dibenzocyclooctene Synthesis via Cobalt(III)–Carbene Radical and ortho‐Quinodimethane Intermediates
por: te Grotenhuis, Colet, et al.
Publicado: (2017)

Cobalt Diazo‐Compounds: From Nitrilimide to Isocyanoamide via a Diazomethanediide Fleeting Intermediate
por: Aghazada, Sadig, et al.
Publicado: (2021)

Mechanistic Insights into Nitrile Activation by Cobalt(III)–Hydroperoxo Intermediates: The Influence of Ligand Basicity
por: Son, Yeongjin, et al.
Publicado: (2023)

A Mononuclear and High-Spin Tetrahedral Ti(II) Complex
por: Reinholdt, Anders, et al.
Publicado: (2020)

Dynamic effects on ligand field from rapid hydride motion in an iron(ii) dimer with an S = 3 ground state
por: McWilliams, Sean F., et al.
Publicado: (2023)

Persistent nucleation and size dependent attachment kinetics produce monodisperse PbS nanocrystals
por: Abécassis, Benjamin, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_bfccbrdtkqofijve9mnanof0vf